Synthesis of In/InP core-shell nanospheres and their transformation into InP hollow nanospheres

被引:10
|
作者
Bao, Keyan
Shi, Liang
Liu, Shuzhen
Xiong, Shenglin
Hu, Xiaobo
Qian, Yitai [1 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Nanostructures; Crystal growth; X-ray diffraction; Luminescence; INDIUM-PHOSPHIDE NANOWIRES; SPHERES; NANOCRYSTALS; MICROSPHERES; GROWTH; NANOSTRUCTURES; FABRICATION; ROUTE; SIZE; GAP;
D O I
10.1016/j.jallcom.2008.04.076
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polycrystalline InP hollow nanospheres with an average size of 520 nm and shell thickness of about 110 nm were obtained by acid treatment of In/InP core-shell nanospheres which were solvothermally synthesized in ethanolamine-water binary solution at 180 degrees C. The sizes of InP hollow nanospheres increased with the increasing reactants quantities. Meanwhile the shell thicknesses of InP hollow nanospheres could be controlled by varying the quantity of yellow phosphorus. The process of In/InP core-shell nanospheres transforming into InP hollow nanospheres was also investigated. The InP products prepared in our experiments can emit blue light, which is different from previous reports and increases the potential application of InP nanomaterial. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 64
页数:6
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