Bioconcentration and bioassembly of N/S co-doped carbon with excellent stability for supercapacitors

被引:75
作者
Lei, Jia [1 ,2 ,3 ]
Guo, Qi [1 ]
Yin, Dingrui [1 ]
Cui, Xudong [4 ]
He, Rong [1 ]
Duan, Tao [1 ,2 ,3 ]
Zhu, Wenkun [1 ,2 ,3 ]
机构
[1] Southwest Univ Sci & Technol, Sch Natl Def Sci & Technol, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China
[2] Southwest Univ Sci & Technol, Natl Collaborat Innovat Ctr Nucl Waste & Environm, Mianyang 621010, Sichuan, Peoples R China
[3] Southwest Univ Sci & Technol, Nucl Waste & Environm Safety Key Lab Def, Mianyang 621010, Sichuan, Peoples R China
[4] CAEP, Inst Chem Mat, Sichuan New Mat Res Ctr, Chengdu 610200, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
Bioconcentration; Bioassembly; Fungal hyphae; Supercapacitors; HIGH-PERFORMANCE ADSORBENTS; ELECTRODE MATERIAL; HIGH CAPACITANCE; OXIDE COMPOSITE; NITROGEN; GRAPHENE; BIOMASS; SULFUR; GROWTH; ELECTROCATALYST;
D O I
10.1016/j.apsusc.2019.05.136
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, we demonstrate a general strategy for the preparation of nitrogen/sulfur co-doped carbon material based on hyphal bioconcentration and bioassembly, where L-cysteine and graphene oxide are added during the growth of fungal hyphae. Carbonization temperature-dependent structure and capacitance performances are discussed in detail. The results show that nitrogen/sulfur co-doped carbon obtained at carbonization temperature of 800 degrees C has high specific capacitance of 206 F g(-1) and good rate capability of 86.1% from 1 to 20 A g(-1). In addition, it shows excellent stability, including favorable temperature stability under extreme conditions (203.3 F g(-1) at 60 degrees C and 199.9 F g(-1) at 0 degrees C water bath), and superior capacitance stability of 93.4% retention after 10,000 cycles. The results indicate that the nitrogen/sulfur co-doped carbon material is a practically potential electrode material for supercapacitors.
引用
收藏
页码:316 / 325
页数:10
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