Hexanuclear Cylinder-Shaped Assemblies of Silver and Gold from Benzene Hexa-N-heterocyclic Carbenes

被引：81

作者：

Segarra, Candela ^{[1
]}

Guisado-Barrios, Gregorio ^{[1
]}

Hahn, F. Ekkehardt ^{[2
]}

Peris, Eduardo ^{[1
]}

机构：

[1] Univ Jaume 1, Dept Quim Inorgan & Organ, E-12071 Castellon de La Plana, Spain

[2] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

来源：

ORGANOMETALLICS | 2014年 / 33卷 / 19期

关键词：

DICARBENE BUILDING-BLOCKS; CATALYTIC APPLICATIONS; STRUCTURAL FEATURES; POLYCARBENE LIGANDS; MOLECULAR SQUARE; COMPLEXES; COORDINATION; POLYMERS; STRATEGY; ANIONS;

D O I：

10.1021/om500729b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work we describe the preparation of a new benzenehexaimidazolylidene ligand, which we have coordinated to silver and gold. The new complexes constitute unique examples of cylinder-like macromolecular arrangements, in which six metal atoms are sandwiched between two hexacarbene ligands.

引用

页码：5077 / 5080

页数：4

共 38 条

[1] Confined Nanospaces in Metallocages: Guest Molecules, Weakly Encapsulated Anions, and Catalyst Sequestration [J].

Amouri, Hani ;

Desmarets, Christophe ;

Moussa, Jamal .

CHEMICAL REVIEWS, 2012, 112 (04) :2015-2041

[2] Bis(imidazolylidene)s as modular building blocks for monomeric and macromolecular organometallic materials [J].

Boydston, Andrew J. ;

Bielawski, Christopher W. .

DALTON TRANSACTIONS, 2006, (34) :4073-4077

[3] Carbene Transfer from Triazolylidene Gold Complexes as a Potent Strategy for Inducing High Catalytic Activity [J].

Canseco-Gonzalez, Daniel ;

Petronilho, Ana ;

Mueller-Bunz, Helge ;

Ohmatsu, Kohsuke ;

Ooi, Takashi ;

Albrecht, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (35) :13193-13203

[4]

CHAKRABARTY R, 2011, CHEM REV, V111, P6810, DOI DOI 10.1021/cr200077m

[5] Organometallic Hollow Spheres Bearing Bis(N-Heterocyclic Carbene)-Palladium Species: Catalytic Application in Three-Component Strecker Reactions [J].

Choi, Jaewon ;

Yang, Hye Yun ;

Kim, Hae Jin ;

Son, Seung Uk .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (42) :7718-7722

[6] Stepwise Formation of a Molecular Square with Bridging NH,O-Substituted Dicarbene Building Blocks [J].

Conrady, Fabian M. ;

Froehlich, Roland ;

Brinke, Christian Schulte To ;

Pape, Tania ;

Hahn, F. Ekkehardt .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) :11496-11499

[7] Supramolecular arrays based on dimetal building units [J].

Cotton, FA ;

Lin, C ;

Murillo, CA .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (10) :759-771

[8] Metallo-supramolecular capsules [J].

Dalgarno, Scott J. ;

Power, Nicholas P. ;

Atwood, Jerry L. .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (8-9) :825-841

[9] Supramolecular concepts and new techniques in mechanochemistry: cocrystals, cages, rotaxanes, open metal-organic frameworks [J].

Friscic, Tomislav .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (09) :3493-3510

[10] Transition-metal-directed assembly of well-defined organic architectures possessing large voids: From macrocycles to [2]catenanes [J].

Fujita, M ;

Ogura, K .

COORDINATION CHEMISTRY REVIEWS, 1996, 148 :249-264

← 1 2 3 4 →