Catalytic Hydrodeoxygenation of Bio-Oils Derived from Pyrolysis of Cork Oak Using Supercritical Ethanol

被引:5
作者
Lee, In-Gu [1 ]
Lee, Heejin [2 ]
Park, Sung Hoon [3 ]
Jung, Sang-Chul [3 ]
Kim, Sang Chai [4 ]
Ko, Chang Hyun [5 ]
Park, Young-Kwon [2 ]
机构
[1] Korea Inst Energy Res, Biomass & Waste Energy Lab, Daejeon 34129, South Korea
[2] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea
[3] Sunchon Natl Univ, Dept Environm Engn, Sunchon 57922, South Korea
[4] Mokpo Natl Univ, Dept Environm Educ, Muan 58554, South Korea
[5] Chonnam Natl Univ, Sch Chem Engn, Gwangju 61186, South Korea
关键词
Bio-Oil; Hydrodeoxygenation; Supercritical Ethanol; Upgrading; Storage; WOODY BIOMASS; HYDROTREATMENT; LIQUEFACTION; CONVERSION; GUAIACOL; FUELS; RU/C; CO2;
D O I
10.1166/jnn.2017.13348
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrodeoxygenation (HDO) of pyrolysis bio-oil produced from cork oak was carried out in supercritical ethanol. Three typical HDO catalysts Pt/Al2O3, Ni/HY, and Pd/Carbon were used. In order to compare the characteristics of raw bio-oil and catalytically reformed HDO oil, the measurement of pH, water content, and viscosity as well as elemental and composition analyses were conducted. The aging assessment based on acids content and higher heating value was performed to evaluate the stability of oils as fuel. The order of stability of the HDO oils was Pt/Al2O3 > Pd/Carbon > Ni/HY. In particular, the HDO oil obtained using Al2O3 catalyst was affected little by aging.
引用
收藏
页码:2674 / 2677
页数:4
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