Catalytic Hydrodeoxygenation of Bio-Oils Derived from Pyrolysis of Cork Oak Using Supercritical Ethanol

被引:5
作者
Lee, In-Gu [1 ]
Lee, Heejin [2 ]
Park, Sung Hoon [3 ]
Jung, Sang-Chul [3 ]
Kim, Sang Chai [4 ]
Ko, Chang Hyun [5 ]
Park, Young-Kwon [2 ]
机构
[1] Korea Inst Energy Res, Biomass & Waste Energy Lab, Daejeon 34129, South Korea
[2] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea
[3] Sunchon Natl Univ, Dept Environm Engn, Sunchon 57922, South Korea
[4] Mokpo Natl Univ, Dept Environm Educ, Muan 58554, South Korea
[5] Chonnam Natl Univ, Sch Chem Engn, Gwangju 61186, South Korea
关键词
Bio-Oil; Hydrodeoxygenation; Supercritical Ethanol; Upgrading; Storage; WOODY BIOMASS; HYDROTREATMENT; LIQUEFACTION; CONVERSION; GUAIACOL; FUELS; RU/C; CO2;
D O I
10.1166/jnn.2017.13348
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrodeoxygenation (HDO) of pyrolysis bio-oil produced from cork oak was carried out in supercritical ethanol. Three typical HDO catalysts Pt/Al2O3, Ni/HY, and Pd/Carbon were used. In order to compare the characteristics of raw bio-oil and catalytically reformed HDO oil, the measurement of pH, water content, and viscosity as well as elemental and composition analyses were conducted. The aging assessment based on acids content and higher heating value was performed to evaluate the stability of oils as fuel. The order of stability of the HDO oils was Pt/Al2O3 > Pd/Carbon > Ni/HY. In particular, the HDO oil obtained using Al2O3 catalyst was affected little by aging.
引用
收藏
页码:2674 / 2677
页数:4
相关论文
共 50 条
  • [31] Influences of pyrolysis conditions in the production and chemical composition of the bio-oils from fast pyrolysis of sewage sludge
    Huang, Xin
    Cao, Jing-Pei
    Shi, Peng
    Zhao, Xiao-Yan
    Feng, Xiao-Bo
    Zhao, Yun-Peng
    Fan, Xing
    Wei, Xian-Yong
    Takarada, Takayuki
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2014, 110 : 353 - 362
  • [32] Non-catalytic upgrading of fast pyrolysis bio-oil in supercritical ethanol and combustion behavior of the upgraded oil
    Prajitno, Hermawan
    Insyani, Rizki
    Park, Jongkeun
    Ryu, Changkook
    Kim, Jaehoon
    APPLIED ENERGY, 2016, 172 : 12 - 22
  • [33] Influence of extraction solvents on the recovery yields and properties of bio-oils from woody biomass liquefaction in sub-critical water, ethanol or water-ethanol mixed solvent
    Zhao, Bojun
    Wang, Haoyu
    Xu, Sida
    Qian, Lixin
    Li, Haoyang
    Gao, Jihui
    Zhao, Guangbo
    Ray, Madhumita B.
    Xu, Chunbao Charles
    FUEL, 2022, 307
  • [34] Catalytic Pyrolysis of Cork Oak Over Supercritical Hydrothermal Synthesized Nanosized ZrO2
    Lee, Yejin
    Park, Rae-Su
    Hong, Yeojin
    Lee, Heejin
    Park, Sung Hoon
    Jung, Sang-Chul
    Kim, Sang Chai
    Jeon, Jong-Ki
    Park, Young-Kwon
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2017, 17 (04) : 2764 - 2767
  • [35] Production of Highly Upgraded Bio-oils through Two-Step Catalytic Pyrolysis of Water Hyacinth
    Hussain, Z.
    Bashir, N.
    Khan, M. I.
    Hussain, K.
    Sulaiman, S. A.
    Naz, M. Y.
    Ibrahim, K. A.
    AbdEl-Salam, N. M.
    ENERGY & FUELS, 2017, 31 (11) : 12100 - 12107
  • [36] Bio-oils from corn stover via supercritical water liquefaction
    Sila Science, Trabzon, Turkey
    Energy Educ. Sct. Technol. Part A. Energy Sci. Res., 2009, 2 (97-104):
  • [37] Chemical and ecotoxicological properties of three bio-oils from pyrolysis of biomasses
    Campisi, Tiziana
    Samori, Chiara
    Torri, Cristian
    Barbera, Giuseppe
    Foschini, Anna
    Kiwan, Alisar
    Galletti, Paola
    Tagliavini, Emilio
    Pasteris, Andrea
    ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2016, 132 : 87 - 93
  • [38] Upgrading Fast Pyrolysis Oil with Vacuum Gas Oil by Catalytic Hydrodeoxygenation in Supercritical Ethanol
    Zhang, Mingyuan
    Pjontek, Dominic
    Wang, Haoyu
    Liu, Minkang
    Han, Xue
    Zeng, Yimin
    Xu, Chunbao
    ENERGY & FUELS, 2024, 38 (11) : 9794 - 9803
  • [39] Microwave pyrolysis of Laminaria digitata to produce unique seaweed-derived bio-oils
    Kostas, Emily T.
    Williams, Orla S. A.
    Duran-Jimenez, Gabriela
    Tapper, Andrew J.
    Cooper, Mick
    Meehan, Richard
    Robinson, John P.
    BIOMASS & BIOENERGY, 2019, 125 : 41 - 49
  • [40] Hydrodeoxygenation of a bio-oil model compound derived from woody biomass using spray-pyrolysis-derived spherical γ-Al2O3-SiO2 catalysts
    Tran, Quoc Khanh
    Han, Sangjin
    Ly, Hoang Vu
    Kim, Seung-Soo
    Kim, Jinsoo
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2020, 92 : 243 - 251