Spray pyrolyzed β-In2S3 thin films:: Effect of postdeposition annealing

被引:35
作者
John, Teny Theresa
Kartha, C. Sudha
Vijayakumar, K. P. [1 ]
Abe, T.
Kashiwaba, Y.
机构
[1] Cochin Univ Sci & Technol, Dept Phys, Thin Film Photovolta Div, Kochi, Kerala, India
[2] Iwate Univ, Dept Elect & Elect Engn, Morioka, Iwate 0208551, Japan
关键词
spray pyrolysis; In2S3 thin films; vacuum annealing; resistivity; grain size;
D O I
10.1016/j.vacuum.2005.11.046
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Indium sulfide thin films prepared using spray pyrolysis, with In/S ratio 2/3 in the solution, were annealed in vacuum at 300 and 400 degrees C. The effect of this treatment on properties of the films was studied using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, optical absorption, transmission and electrical measurements. Optical constants of the films were calculated using the envelope method. Annealing did not affect the optical properties of the film much, but the resistivity of the films showed a drastic decrease and the grain size increased. In2S3 thin films have potential use as buffer layer in photovoltaic heterojunction devices. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:870 / 875
页数:6
相关论文
共 26 条
[1]   Acoustic properties of β-In2S3 thin films prepared by spray [J].
Amlouk, M ;
Ben Saïd, MA ;
Kamoun, N ;
Belgacem, S ;
Brunet, N ;
Barjon, D .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1999, 38 (1A) :26-30
[2]   GROWTH OF IN(2)S(3) THIN-FILMS BY ATOMIC LAYER EPITAXY [J].
ASIKAINEN, T ;
RITALA, M ;
LESKELA, M .
APPLIED SURFACE SCIENCE, 1994, 82-3 :122-125
[3]   Structural, optical and electrical properties of β-In2S3-3xO3x thin films obtained by PVD [J].
Barreau, N ;
Marsillac, S ;
Albertini, D ;
Bernede, JC .
THIN SOLID FILMS, 2002, 403 :331-334
[4]   Recent studies on In2S3 containing oxygen thin films [J].
Barreau, N ;
Bernède, JC ;
El Maliki, H ;
Marsillac, S ;
Castel, X ;
Pinel, J .
SOLID STATE COMMUNICATIONS, 2002, 122 (7-8) :445-450
[5]   MOCVD OF GROUP-III CHALCOGENIDES [J].
BARREN, AR .
ADVANCED MATERIALS FOR OPTICS AND ELECTRONICS, 1995, 5 (05) :245-258
[6]  
Bhira L, 2000, PHYS STATUS SOLIDI A, V181, P427, DOI 10.1002/1521-396X(200010)181:2<427::AID-PSSA427>3.0.CO
[7]  
2-P
[8]   An 11.4% efficient polycrystalline thin film solar cell based on CuInS2 with a Cd-free buffer layer [J].
Braunger, D ;
Hariskos, D ;
Walter, T ;
Schock, HW .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1996, 40 (02) :97-102
[9]   REACTIVELY EVAPORATED-FILMS OF INDIUM SULFIDE [J].
GEORGE, J ;
JOSEPH, KS ;
PRADEEP, B ;
PALSON, TI .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1988, 106 (01) :123-131
[10]   A novel cadmium free buffer layer for Cu(In,Ga)Se-2 based solar cells [J].
Hariskos, D ;
Ruckh, M ;
Ruhle, U ;
Walter, T ;
Schock, HW ;
Hedstrom, J ;
Stolt, L .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1996, 41-2 :345-353