3D Fe2(MoO4)3 microspheres with nanosheet constituents as high-capacity anode materials for lithium-ion batteries

被引:23
作者
Zheng, Hao [1 ,2 ]
Wang, Shiqiang [1 ,2 ]
Wang, Jiazhao [3 ]
Wang, Jun [3 ]
Li, Lin [1 ,2 ]
Yang, Yun [1 ,2 ]
Feng, Chuanqi [1 ,2 ]
Sun, Ziqi [4 ]
机构
[1] Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
[2] Anshun Univ, Key Lab Funct Mat & Chem Performance & Resources, Guizhou Educ Dept, Anshun 561000, Peoples R China
[3] Univ Wollongong, Inst Superconducting & Elect Mat, North Wollongong, NSW 2500, Australia
[4] Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia
关键词
Inorganic compounds; Chemical synthesis; Nanostructures; Electrochemical properties; Energy storage; NANOSTRUCTURED MATERIALS; GENERAL-SYNTHESIS; MORPHOLOGY; ELECTRODE; NANORODS; GROWTH; COMOO4; NIMOO4; MN; NI;
D O I
10.1007/s11051-015-3254-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three-dimensional (3D) Fe-2(MoO4)(3) microspheres with ultrathin nanosheet constituents are first synthesized as anode materials for the lithium-ion battery. It is interesting that the single-crystalline nanosheets allow rapid electron/ion transport on the inside, and the high porosity ensures fast diffusion of liquid electrolyte in energy storage applications. The electrochemical properties of Fe-2(MoO4)(3) as anode demonstrates that 3D Fe-2(MoO4)(3) microspheres deliver an initial capacity of 1855 mAh/g at a current density of 100 mA/g. Particularly, when the current density is increased to 800 mA/g, the reversible capacity of Fe-2(MoO4)(3) anode still arrived at 456 mAh/g over 50 cycles. The large and reversible capacities and stable charge-discharge cycling performance indicate that Fe-2(MoO4)(3) is a promising anode material for lithium battery applications.
引用
收藏
页码:1 / 8
页数:8
相关论文
共 35 条
  • [1] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [2] A simple aqueous mineralization process to synthesize tetragonal molybdate microcrystallites
    Chen, D
    Tang, KB
    Li, FQ
    Zheng, HG
    [J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (01) : 247 - 252
  • [3] α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications
    Chen, J
    Xu, LN
    Li, WY
    Gou, XL
    [J]. ADVANCED MATERIALS, 2005, 17 (05) : 582 - +
  • [4] Functional Materials for Rechargeable Batteries
    Cheng, Fangyi
    Liang, Jing
    Tao, Zhanliang
    Chen, Jun
    [J]. ADVANCED MATERIALS, 2011, 23 (15) : 1695 - 1715
  • [5] Interconnected Network of CoMoO4 Submicrometer Particles As High Capacity Anode Material for Lithium Ion Batteries
    Cherian, Christie T.
    Reddy, M. V.
    Haur, Sow Chorng
    Chowdari, B. V. R.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (03) : 918 - 923
  • [6] Catalyst-Free Growth of Quasi-Aligned Nanorods of Single Crystal Cu3Mo2O9 and Their Catalytic Properties
    Chu, W. G.
    Wang, H. F.
    Guo, Y. J.
    Zhang, L. N.
    Han, Z. H.
    Li, Q. Q.
    Fan, S. S.
    [J]. INORGANIC CHEMISTRY, 2009, 48 (03) : 1243 - 1249
  • [7] Formation of FeMoO4 hollow microspheres via a chemical conversion-induced Ostwald ripening process
    Cui, Jian-Xun
    Wang, Wen-Shou
    Zhen, Liang
    Shao, Wen-Zhu
    Chen, Zhong-Lin
    [J]. CRYSTENGCOMM, 2012, 14 (20): : 7025 - 7030
  • [8] Carbothermal synthesis, spectral and magnetic characterization and Li-cyclability of the Mo-cluster compounds, LiYMo3O8 and Mn2Mo3O8
    Das, B.
    Reddy, M. V.
    Krishnamoorthi, C.
    Tripathy, S.
    Mahendiran, R.
    Rao, G. V. Subba
    Chowdari, B. V. R.
    [J]. ELECTROCHIMICA ACTA, 2009, 54 (12) : 3360 - 3373
  • [9] General synthesis and phase control of metal molybdate hydrates MMoO4•nH2O (M = Co, Ni, Mn, n=0, 3/4, 1) nano/microcrystals by a hydrothermal approach:: Magnetic, photocatalytic, and electrochemical properties
    Ding, Yi
    Wan, Yong
    Min, Yu-Lin
    Zhang, Wei
    Yu, Shu-Hong
    [J]. INORGANIC CHEMISTRY, 2008, 47 (17) : 7813 - 7823
  • [10] Nanostructured materials for electrochemical energy conversion and storage devices
    Guo, Yu-Guo
    Hu, Jin-Song
    Wan, Li-Jun
    [J]. ADVANCED MATERIALS, 2008, 20 (15) : 2878 - 2887