A Compactly Fused π-Conjugated Tetrathiafulvalene-Perylenediimide Donor-Acceptor Dyad

被引：43

作者：

Jaggi, Michael ^{[1
]}

Blum, Carmen ^{[1
]}

Dupont, Nathalie ^{[2
]}

Grilj, Jakob ^{[2
]}

Liu, Shi-Xia ^{[1
]}

Hauser, Juerg ^{[1
]}

Hauser, Andreas ^{[2
]}

Decurtins, Silvio ^{[1
]}

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[2] Univ Geneva, Dept Chim Phys, CH-1211 Geneva 4, Switzerland

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 14期

基金：

瑞士国家科学基金会;

关键词：

INTRAMOLECULAR CHARGE-TRANSFER; ELECTRON-TRANSFER; TTF; DERIVATIVES; DIIMIDE; MOLECULES; BISIMIDE; FLUORESCENT; PORPHYRIN; ARRAYS;

D O I：

10.1021/ol901186n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and structural characterization of a tetrathiafulvalene-fused perylenediimide molecular dyad is presented. Its largely extended pi-conjugation provides Intense optical absorption bands over a wide spectral range. The planar functional molecule exhibits a short-lived nonluminescent excited state attributed to intramolecular charge separation.

引用

页码：3096 / 3099

页数：4

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