Nonequilibrium Casimir pressures in liquids under shear

被引:2
作者
Ortiz de Zarate, J. M. [1 ]
Kirkpatrick, T. R. [2 ]
Sengers, J., V [2 ]
机构
[1] Univ Complutense, Fac Fis, Dept Estruct Mat, E-28040 Madrid, Spain
[2] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
关键词
Flowing Matter; Liquids and Complex Fluids; MODE-COUPLING THEORY; LONG-TIME TAILS; HYDRODYNAMIC FLUCTUATIONS; STRESS-TENSOR; MOLECULAR-DYNAMICS; VISCOSITY; HARD; TRANSITION; BEHAVIOR;
D O I
10.1140/epje/i2019-11868-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In stationary nonequilibrium states coupling between hydrodynamic modes causes thermal fluctuations to become long ranged inducing nonequilibrium Casimir pressures. Here we consider nonequilibrium Casimir pressures induced in liquids by a velocity gradient. Specifically, we have obtained explicit expressions for the magnitude of the shear-induced pressure enhancements in a liquid layer between two horizontal plates that complete and correct results previously presented in the literature. In contrast to nonequilibrium Casimir pressures induced by a temperature or concentration gradient, we find that in shear nonequilibrium contributions from short-range fluctuations are no longer negligible. In addition, it is noted that currently available computer simulations of model fluids in shear observe effects from molecular correlations at nanoscales that have a different physical origin and do not probe shear-induced pressures resulting from coupling of long-wavelength hydrodynamic modes. Even more importantly, we find that in actual experimental conditions, shear-induced pressure enhancements are caused by viscous heating and not by thermal velocity fluctuations. Hence, isothermal computer simulations are irrelevant for the interpretation of experimental shear-induced pressure enhancements.
引用
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页数:12
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