Halogen Bond and Free Internal Rotation: The Microwave Spectrum of CF3Cl-Dimethyl Ether

被引：32

作者：

Evangelisti, Luca ^{[1
]}

Feng, Gang ^{[1
]}

Gou, Qian ^{[1
]}

Grabow, Jens-Uwe ^{[1
]}

Caminati, Walther ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2014年 / 118卷 / 03期

关键词：

HYDROGEN-BOND; GAS-PHASE; COMPLEXES; CHEMISTRY; CL;

D O I：

10.1021/jp411372m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rotational spectra of two isotopologues of the molecular complex CF3Cl-dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl center dot center dot center dot O halogen bond, and on the almost free rotation of the -CF3 group.

引用

收藏

页码：579 / 582

页数：4

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