Ultrathin PtPdTe Nanowires as Superior Catalysts for Methanol Electrooxidation

被引:215
作者
Li, Hui-Hui [1 ]
Zhao, Shuo [1 ]
Gong, Ming [2 ]
Cui, Chun-Hua [1 ]
He, Da [1 ]
Liang, Hai-Wei [1 ]
Wu, Liang [1 ]
Yu, Shu-Hong [1 ]
机构
[1] Univ Sci & Technol China, Div Nanomat & Chem, Hefei Natl Lab Phys Sci Microscale, Dept Chem, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Engn & Mat Sci Expt Ctr, Hefei 230026, Peoples R China
基金
中国国家自然科学基金; 对外科技合作项目(国际科技项目);
关键词
electrocatalysts; heterogeneous catalysis; methanol oxidation; nanowires; platinum; ENHANCED ELECTROCATALYTIC ACTIVITY; BIMETALLIC NANODENDRITES; NANOPARTICLE TUBES; EXCELLENT PLATFORM; ALLOY NANOWIRES; OXIDATION; NANOCRYSTALS; PLATINUM; ETHANOL; PERFORMANCE;
D O I
10.1002/anie.201302090
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrathin and ultralong: Highly uniform, ultrathin (diameter 5-7 nm), and ultralong (aspect ratio >104) PtPdTe nanowires (NWs) were synthesized by using a facile method employing Te NWs as both sacrificial templates and reducing agents. Fine-tuning of the molar ratios of Pt and Pd precursors afforded PtPdTe NWs with different compositions and enhanced electroactivity in the methanol oxidation reaction in comparison with a commercial Pt/C catalyst. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:7472 / 7476
页数:5
相关论文
共 55 条
[1]   Nanoceria-Modified Platinum-Gold Composite Electrodes for the Electrochemical Oxidation of Methanol and Ethanol in Acidic Media [J].
Anderson, Jordan ;
Karakoti, Ajay ;
Diaz, Diego J. ;
Seal, Sudipta .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (10) :4595-4602
[2]  
[Anonymous], 2013, ANGEW CHEM INT ED
[3]   Ultrathin Nanowires - A Materials Chemistry Perspective [J].
Cademartiri, Ludovico ;
Ozin, Geoffrey A. .
ADVANCED MATERIALS, 2009, 21 (09) :1013-1020
[4]   Opportunities and challenges for a sustainable energy future [J].
Chu, Steven ;
Majumdar, Arun .
NATURE, 2012, 488 (7411) :294-303
[5]  
Cui C.-H., 2010, ANGEW CHEM, V122, P9335
[6]   Engineering Interface and Surface of Noble Metal Nanoparticle Nanotubes toward Enhanced Catalytic Activity for Fuel Cell Applications [J].
Cui, Chun-Hua ;
Yu, Shu-Hong .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (07) :1427-1437
[7]   Ternary PtPdCu Electrocatalyst Formed through Surface-Atomic Redistribution against Leaching [J].
Cui, Chun-Hua ;
Liu, Xiao-Jing ;
Li, Hui-Hui ;
Gao, Min-Rui ;
Liang, Hai-Wei ;
Yao, Hong-Bin ;
Yu, Shu-Hong .
CHEMCATCHEM, 2012, 4 (10) :1560-1563
[8]   Surface Composition and Lattice Ordering-Controlled Activity and Durability of CuPt Electrocatalysts for Oxygen Reduction Reaction [J].
Cui, Chun-Hua ;
Li, Hui-Hui ;
Liu, Xiao-Jing ;
Gao, Min-Rui ;
Yu, Shu-Hong .
ACS CATALYSIS, 2012, 2 (06) :916-924
[9]   Large scale restructuring of porous Pt-Ni nanoparticle tubes for methanol oxidation: A highly reactive, stable, and restorable fuel cell catalyst [J].
Cui, Chun-Hua ;
Li, Hui-Hui ;
Yu, Shu-Hong .
CHEMICAL SCIENCE, 2011, 2 (08) :1611-1614
[10]   Remarkable Enhancement of Electrocatalytic Activity by Tuning the Interface of Pd-Au Bimetallic Nanoparticle Tubes [J].
Cui, Chun-Hua ;
Yu, Jin-Wen ;
Li, Hui-Hui ;
Gao, Min-Rui ;
Liang, Hai-Wei ;
Yu, Shu-Hong .
ACS NANO, 2011, 5 (05) :4211-4218