Nonenzymatic kinetic resolution of racemic α-hydroxyalkanephosphonates with chiral copper catalyst

被引：9
作者：
Demizu, Yosuke [1 ]
Moriyama, Atsushi [1 ]
Onomura, Osamu [1 ]
机构：
[1] Nagasaki Univ, Grad Sch Biomed Sci, Nagasaki 8528521, Japan
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 37期
关键词：
Kinetic resolution; Asymmetric benzoylation; alpha-Hydroxyalkanephosphonates; Chiral copper complex; Molecular recognition; MESO-VIC-DIOLS; CU(II) COMPLEX; ENANTIOSELECTIVE SYNTHESIS; ALDEHYDES; PHOSPHONATES; HYDROPHOSPHONYLATION; OXIDATION; 1,2-DIOLS; ALDIMINES; PHOSPHITE;
D O I：
10.1016/j.tetlet.2009.07.003
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Kinetic resolution of alpha-hydroxyalkanephosphonates was efficiently performed by benzoylation in the presence of copper(II) triflate and (R,R)-Ph-BOX as a catalyst with excellent s value of up to 286. (C) 2009 Elsevier Ltd. All rights reserved.
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收藏
页码：5241 / 5244
页数：4
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