A p-Type NiO-Based Dye-Sensitized Solar Cell with an Open-Circuit Voltage of 0.35 V

被引：240

作者：

Gibson, Elizabeth A. ^{[2
]}

Smeigh, Amanda L. ^{[3
]}

Le Pleux, Loic ^{[1
]}

Fortage, Jerome ^{[1
]}

Boschloo, Gerrit ^{[2
]}

Blart, Errol ^{[1
]}

Pellegrin, Yann ^{[1
]}

Odobel, Fabrice ^{[1
]}

Hagfeldt, Anders ^{[2
,4
]}

Hammarstrom, Leif ^{[3
]}

机构：

[1] Univ Nantes, CEISAM, Fac Sci & Tech, F-44322 Nantes 3, France

[2] Uppsala Univ, Dept Phys & Analyt Chem, SE-75105 Uppsala, Sweden

[3] Uppsala Univ, Dept Photochem & Mol Sci, SE-75120 Uppsala, Sweden

[4] Royal Inst Technol, Dept Chem, Ctr Mol Devices, SE-10044 Stockholm, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 24期

关键词：

donor-acceptor systems; dye-sensitized solar cells; electrolytes; energy conversion; sustainable chemistry; REDOX COUPLE; CONVERSION EFFICIENCY; CHARGE RECOMBINATION; ELECTRON-TRANSFER; PHOTOCATHODE; FILMS; FABRICATION;

D O I：

10.1002/anie.200900423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In tandem: Employing a molecular dyad and a cobalt-based electrolyte gives a threefoldincrease in open-circuit voltage (VOC) for a p-type NiO device (VOC=0.35 V), and a fourfold better energy conversion efficiency. Incorporating these improvements in a TiO2/NiO tandem dyesensitized solar cell (TDSC), results in a TDSC with a VOC=0.91 V (see figure; CB=conductance band, VB= valence band). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4402 / 4405

页数：4

共 24 条

[1] Distance-independent photoinduced energy transfer over 1.1 to 2.3 nm in ruthenium trisbipyridine-fullerene assemblies
Chaignon, F
Torroba, J
Blart, E
Borgström, M
Hammarström, L
Odobel, F
[J]. NEW JOURNAL OF CHEMISTRY, 2005, 29 (10) : 1272 - 1284
[2] Solar energy conversion by dye-sensitized photovoltaic cells
Grätzel, M
[J]. INORGANIC CHEMISTRY, 2005, 44 (20) : 6841 - 6851
[3] Molecular photovoltaics
Hagfeldt, A
Grätzel, M
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 269 - 277
[4] Dye-sensitized nanostructured p-type nickel oxide film as a photocathode for a solar cell
He, JJ
Lindström, H
Hagfeldt, A
Lindquist, SE
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (42): : 8940 - 8943
[5] Dye-sensitized nanostructured tandem cell-first demonstrated cell with a dye-sensitized photocathode
He, JJ
Lindström, H
Hagfeldt, A
Lindquist, SE
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 62 (03) : 265 - 273
[6] Control of dark current in photoelectrochemical (TiO2/I--I3-) and dye-sensitized solar cells
Ito, S
Liska, P
Comte, P
Charvet, RL
Péchy, P
Bach, U
Schmidt-Mende, L
Zakeeruddin, SM
Kay, A
Nazeeruddin, MK
Grätzel, M
[J]. CHEMICAL COMMUNICATIONS, 2005, (34) : 4351 - 4353
[7] Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%
Ito, Seigo
Murakami, Takurou N.
Comte, Pascal
Liska, Paul
Graetzel, Carole
Nazeeruddin, Mohammad K.
Graetzel, Michael
[J]. THIN SOLID FILMS, 2008, 516 (14) : 4613 - 4619
[8] Fabrication of dye-sensitized solar cells with an open-circuit photovoltage of 1 V
Iwamoto, Shinji
Sazanami, Yohei
Inoue, Masashi
Inoue, Teruhisa
Hoshi, Takayuki
Shigaki, Koichiro
Kaneko, Masayoshi
Maenosono, Akira
[J]. CHEMSUSCHEM, 2008, 1 (05) : 401 - 403
[9] Nanocrystalline dye-sensitized solar cells having maximum performance
Kroon, J. M.
Bakker, N. J.
Smit, H. J. P.
Liska, P.
Thampi, K. R.
Wang, P.
Zakeeruddin, S. M.
Gratzel, M.
Hinsch, A.
Hore, S.
Wurfel, U.
Sastrawan, R.
Durrant, J. R.
Palomares, E.
Pettersson, H.
Gruszecki, T.
Walter, J.
Skupien, K.
Tulloch, G. E.
[J]. PROGRESS IN PHOTOVOLTAICS, 2007, 15 (01): : 1 - 18
[10] Photoinduced ultrafast dynamics of coumarin 343 sensitized p-type-nanostructured NiO films
Morandeira, A
Boschloo, G
Hagfeldt, A
Hammarström, L
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (41) : 19403 - 19410

← 1 2 3 →