Solid lithium ion conducting composites based on LiTi2(PO4)3 and Li2.9B0.9S0.1O3.1 glass

被引：12
作者：
Kwatek, K. [1 ]
Nowinski, J. L. [1 ]
机构：
[1] Warsaw Univ Technol, Fac Phys, PL-00662 Warsaw, Poland
来源：
SOLID STATE IONICS | 2018年 / 322卷
关键词：
Solid electrolyte; Impedance spectroscopy; Grain boundary; Composite; LTP; LOW-TEMPERATURE SYNTHESIS; TITANIUM PHOSPHATE; IMPEDANCE/DIELECTRIC SPECTROSCOPY; SYSTEM LI2O-AL2O3-TIO2-P2O5; POLYCRYSTALLINE CERAMICS; ELECTRICAL-PROPERTIES; THEORETICAL-ANALYSIS; OXYSULFIDE GLASSES; GRAIN-BOUNDARIES; GEL PROCESS;
D O I：
10.1016/j.ssi.2018.05.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The LiTi2(PO4)(3)-based ceramic composites with addition of Li2.9B0.9S0.1O3.1 (LBSO) were formed and investigated by means of X-ray diffractometry, thermogravimetry, scanning electron microscopy, impedance spectroscopy and density methods. Significant enhancement of total ionic conductivity of the formed composites could be observed after sintering the material at high temperatures. The maximum conductivity of 1.79 x 10(-4) S.cm(-1) at 30 degrees C was achieved for the LTP-0.3LBSO material sintered at 900 degrees C compared to 5.15 x 10(-8) S.cm(-1) of the ceramic LTP.
引用
收藏
页码：93 / 99
页数：7
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