Oxygen exchange materials for solar thermochemical splitting of H2O and CO2: a review

被引：315
作者：
Scheffe, Jonathan R. [1 ]
Steinfeld, Aldo [1 ,2 ]
机构：
[1] ETH, Dept Mech & Proc Engn, CH-8092 Zurich, Switzerland
[2] Paul Scherrer Inst, Solar Technol Lab, CH-5232 Villigen, Switzerland
来源：
MATERIALS TODAY | 2014年 / 17卷 / 07期
基金：
欧洲研究理事会;
关键词：
HYDROGEN-PRODUCTION; IRON-OXIDE; THERMODYNAMIC ANALYSIS; CATION DIFFUSION; DEFECT STRUCTURE; WATER; TEMPERATURE; CYCLE; CERIA; NONSTOICHIOMETRY;
D O I：
10.1016/j.mattod.2014.04.025
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This review summarizes state of the art metal oxide materials used in two-step thermochemical redox cycles for the production of H-2 and CO from H2O and CO2 using concentrated solar energy. Advantages and disadvantages of both stoichiometric (e. g. iron oxide based cycles) and nonstoichiometric (e. g. ceria based cycles) materials are discussed in the context of thermodynamics, chemical kinetics, and material stability. Finally, a perspective aimed at future materials development and requirements necessary for advances of process efficiencies is discussed.
引用
收藏
页码：341 / 348
页数：8
相关论文
共 72 条
  • [41] First-principles thermodynamic framework for the evaluation of thermochemical H2O- or CO2-splitting materials
    Meredig, B.
    Wolverton, C.
    [J]. PHYSICAL REVIEW B, 2009, 80 (24)
  • [42] Physical, chemical and electrochemical properties of pure and doped ceria
    Mogensen, M
    Sammes, NM
    Tompsett, GA
    [J]. SOLID STATE IONICS, 2000, 129 (1-4) : 63 - 94
  • [43] Efficient Generation of H2 by Splitting Water with an Isothermal Redox Cycle
    Muhich, Christopher L.
    Evanko, Brian W.
    Weston, Kayla C.
    Lichty, Paul
    Liang, Xinhua
    Martinek, Janna
    Musgrave, Charles B.
    Weimer, Alan W.
    [J]. SCIENCE, 2013, 341 (6145) : 540 - 542
  • [44] HYDROGEN PRODUCTION FROM WATER UTILIZING SOLAR HEAT AT HIGH-TEMPERATURES
    NAKAMURA, T
    [J]. SOLAR ENERGY, 1977, 19 (05) : 467 - 475
  • [45] PRODUCTION OF CARBON-MONOXIDE BY DIRECT THERMAL SPLITTING OF CARBON-DIOXIDE AT HIGH-TEMPERATURE
    NIGARA, Y
    CALES, B
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (06) : 1997 - 2002
  • [46] DEFECT STRUCTURE AND THERMODYNAMIC PROPERTIES OF THE WUSTITE PHASE (FE1-YO)
    NOWOTNY, J
    REKAS, M
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (07) : 1221 - 1228
  • [47] A THERMODYNAMIC AND ELECTRICAL-CONDUCTIVITY STUDY OF NONSTOICHIOMETRIC CERIUM DIOXIDE
    PANHANS, MA
    BLUMENTHAL, RN
    [J]. SOLID STATE IONICS, 1993, 60 (04) : 279 - 298
  • [48] THERMODYNAMIC STUDY OF NONSTOICHIOMETRIC CERIUM DIOXIDE
    PANLENER, RJ
    BLUMENTHAL, RN
    GARNIER, JE
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1975, 36 (11) : 1213 - 1222
  • [49] Thermal ZnO dissociation in a rapid aerosol reactor as part of a solar hydrogen production cycle
    Perkins, Christopher
    Lichty, Paul R.
    Weimer, Alan W.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (02) : 499 - 510
  • [50] Perrucci R, 2011, SOLV SOC PROB, P1
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