Oxygen exchange materials for solar thermochemical splitting of H2O and CO2: a review

被引：315
作者：
Scheffe, Jonathan R. [1 ]
Steinfeld, Aldo [1 ,2 ]
机构：
[1] ETH, Dept Mech & Proc Engn, CH-8092 Zurich, Switzerland
[2] Paul Scherrer Inst, Solar Technol Lab, CH-5232 Villigen, Switzerland
来源：
MATERIALS TODAY | 2014年 / 17卷 / 07期
基金：
欧洲研究理事会;
关键词：
HYDROGEN-PRODUCTION; IRON-OXIDE; THERMODYNAMIC ANALYSIS; CATION DIFFUSION; DEFECT STRUCTURE; WATER; TEMPERATURE; CYCLE; CERIA; NONSTOICHIOMETRY;
D O I：
10.1016/j.mattod.2014.04.025
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This review summarizes state of the art metal oxide materials used in two-step thermochemical redox cycles for the production of H-2 and CO from H2O and CO2 using concentrated solar energy. Advantages and disadvantages of both stoichiometric (e. g. iron oxide based cycles) and nonstoichiometric (e. g. ceria based cycles) materials are discussed in the context of thermodynamics, chemical kinetics, and material stability. Finally, a perspective aimed at future materials development and requirements necessary for advances of process efficiencies is discussed.
引用
收藏
页码：341 / 348
页数：8
相关论文
共 72 条
  • [1] Thermochemical hydrogen production from a two-step solar-driven water-splitting cycle based on cerium oxides
    Abanades, Stephane
    Flamant, Gilles
    [J]. SOLAR ENERGY, 2006, 80 (12) : 1611 - 1623
  • [2] Investigation of reactive cerium-based oxides for H2 production by thermochemical two-step water-splitting
    Abanades, Stephane
    Legal, Alex
    Cordier, Anne
    Peraudeau, Gilles
    Flamant, Gilles
    Julbe, Anne
    [J]. JOURNAL OF MATERIALS SCIENCE, 2010, 45 (15) : 4163 - 4173
  • [3] Novel two-step SnO2/Sno water-splitting cycle for solar thermochemical production of hydrogen
    Abanades, Stephane
    Charvin, Patrice
    Lemont, Florent
    Flamant, Gilles
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (21) : 6021 - 6030
  • [4] Two-Step Water Splitting Using Mixed-Metal Ferrites: Thermodynamic Analysis and Characterization of Synthesized Materials
    Allendorf, Mark D.
    Diver, Richard B.
    Siegel, Nathan P.
    Miller, James E.
    [J]. ENERGY & FUELS, 2008, 22 (06) : 4115 - 4124
  • [5] Assessing the feasibility of separating a stoichiometric mixture of zinc vapor and oxygen by a fast quench - Model calculations
    Alxneit, Ivo
    [J]. SOLAR ENERGY, 2008, 82 (11) : 959 - 964
  • [6] [Anonymous], 2011, TIAX SUPP COST AN SO, P76
  • [7] CoFe2O4 on a porous Al2O3 nanostructure for solar thermochemical CO2 splitting
    Arifin, Darwin
    Aston, Victoria J.
    Liang, Xinhua
    McDaniel, Anthony H.
    Weimer, Alan W.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (11) : 9438 - 9443
  • [8] Thermodynamic Analysis of Isothermal Redox Cycling of Ceria for Solar Fuel Production
    Bader, Roman
    Venstrom, Luke J.
    Davidson, Jane H.
    Lipinski, Wojciech
    [J]. ENERGY & FUELS, 2013, 27 (09) : 5533 - 5544
  • [9] THERMOGRAVIMETRIC DETERMINATION OF COMPOSITION-OXYGEN PARTIAL PRESSURE DIAGRAM OF WUSTITE (FE1-YO)
    BRANSKY, I
    HED, AZ
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1968, 51 (04) : 231 - &
  • [10] Call F., 2013, Am. J. Anal. Chem, V04, P37, DOI DOI 10.4236/AJAC.2013.410A1005,04(10)
12345678