A series of Mg-rich volcanic rocks, including rare Mg-rich dacites in the Asherle copper mine, western Altay Area, has been found. This suite of Mg-rich volcanic rocks is characterized by high SiO2, MgO and low Ti contents. Compared with the island are tholeiite and MORE, these rocks are depleted in HFSE and are therefore similar to boninite. The dacites show V-shaped distribution REE patterns whereas the basalts display flat or LREE-depletion patterns. Based on their geochemical features and occurrence, it is suggested that they were formed in oceanic island are setting. Its petrogenesis is related to the slab movement. At the early stage, the peridotite of the ocean upper mantle diapirically uprised to the shallow level and started to melt owing to subduction of the ocean slab, forming the island are tholeiite with pillow structure. At the late stage, the residual refractory peridotites melted again, giving rise to the formation of the parent magma of Mg-rich basalt.