An exceptionally stable core-shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization-Knoevenagel condensation reaction

被引:119
作者
Gao, Ming-Liang [1 ]
Qi, Mei-Hong [1 ]
Liu, Lin [1 ]
Han, Zheng-Bo [1 ]
机构
[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORKS; HETEROGENEOUS CATALYSTS; CO2; ADSORPTION; ONE-POT; MOFS; COMPOSITES; ZIRCONIUM; MEMBRANES; POLYMERS;
D O I
10.1039/c9cc02174d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel strategy has been developed to construct a highly stable core-shell MOF@ COF ( PCN-222-Co@ TpPa-1) bifunctional catalyst through strong p-p stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel condensation cascade reaction.
引用
收藏
页码:6377 / 6380
页数:4
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