An exceptionally stable core-shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization-Knoevenagel condensation reaction

被引：119

作者：

Gao, Ming-Liang ^{[1
]}

Qi, Mei-Hong ^{[1
]}

Liu, Lin ^{[1
]}

Han, Zheng-Bo ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 45期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; HETEROGENEOUS CATALYSTS; CO2; ADSORPTION; ONE-POT; MOFS; COMPOSITES; ZIRCONIUM; MEMBRANES; POLYMERS;

D O I：

10.1039/c9cc02174d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel strategy has been developed to construct a highly stable core-shell MOF@ COF ( PCN-222-Co@ TpPa-1) bifunctional catalyst through strong p-p stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel condensation cascade reaction.

引用

页码：6377 / 6380

页数：4

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