Densities and volumetric properties of binary and ternary mixtures of diisopropyl ether, fluorobenzene, α,α,α-trifluorotoluene, and ethanol at temperature 298.15 K and pressure 101 kPa

被引:13
作者
Atik, Zadjia [1 ]
Lourddani, Kenza [1 ]
机构
[1] Univ Sci & Technol Houari Boumediene, Fac Chem, Algiers 16112, Algeria
关键词
alcohol; fluorobenzene; alpha; alpha-trifluorotoluene; diisopropyl ether; density; excess molar volume; ternary mixture; empirical equation; prediction;
D O I
10.1007/s10953-006-9072-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Excess molar volumes of binary mixtures of (fluorobenzene + ethanol), (fluorobenzene + diisopropyl ether), (alpha,alpha,alpha-trifluorotoluene + ethanol), (diisopropyl ether + ethanol), (alpha,alpha,alpha-trifluorotoluene + diisopropyl ether), and the ternary mixtures of (fluorobenzene + diisopropyl ether + ethanol), and (alpha,alpha,alpha-trifluorotoluene + diisopropyl ether + ethanol) were evaluated from density data. The densities were measured with a vibrating-tube densimeter at the temperature 298.15 K and the pressure 101 kPa. The values of the mixing volumes of the ternary systems were predicted in terms of empirical equations using binary solution data alone. The extent of chemical associations among the molecules forming the mixtures is discussed.
引用
收藏
页码:1453 / 1466
页数:14
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