Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

被引：55

作者：

Kawasaki, Tsuneomi ^{[1
,2
]}

Shimizu, Masako ^{[1
]}

Nishiyama, Daisuke ^{[1
]}

Ito, Masateru ^{[1
]}

Ozawa, Hitomi ^{[1
]}

Soai, Kenso ^{[1
,2
]}

机构：

[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Tokyo Univ Sci, Res Inst Sci & Technol, Shinjuku Ku, Tokyo 1628601, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 29期

关键词：

HIGHLY ENANTIOSELECTIVE SYNTHESIS; ENANTIOMERIC EXCESS; SYMMETRY-BREAKING; CHROMATOGRAPHIC-SEPARATION; AMPLIFICATION; HOMOCHIRALITY; ORIGIN; ENRICHMENT; AUTOMULTIPLICATION; HYDROCARBONS;

D O I：

10.1039/b908754k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Achiral meteoritic amino acids, glycine and alpha-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.

引用

收藏

页码：4396 / 4398

页数：3

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