Cooperative ion-exchange and self-redox process to load catalytic metal nanoparticles into a MOF with Johnson-type cages

被引：33
作者：
Tan, Yan-Xi [1 ]
He, Yan-Ping [1 ]
Zhang, Jian [1 ,2 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] China Three Gorges Univ, Coll Mat & Chem Engn, Yichang 443002, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 46期
关键词：
ORGANIC FRAMEWORK; HYDROGEN STORAGE;
D O I：
10.1039/c4cc00468j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Through a cooperative ion-exchange and self-redox process, a new MOF material with nanosized Johnson-type cages has successfully produced Pd- or Ag-NPs in its pores without any external reducing agents, leading to the formation of M-NP-embedded catalysts for the hydrogenation of styrene.
引用
收藏
页码：6153 / 6156
页数：4
相关论文
共 22 条
[1]   Semiconductor behavior of a metal-organic framework (MOF) [J].
Alvaro, Mercedes ;
Carbonell, Esther ;
Ferrer, Belen ;
Llabres i Xamena, Francesc X. ;
Garcia, Hermenegildo .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (18) :5106-5112
[2]   Metal-Organic Framework Single Crystals as Photoactive Matrices for the Generation of Metallic Microstructures [J].
Ameloot, Rob ;
Roeffaers, Maarten B. J. ;
De Cremer, Gert ;
Vermoortele, Frederik ;
Hofkens, Johan ;
Sels, Bert F. ;
De Vos, Dirk E. .
ADVANCED MATERIALS, 2011, 23 (15) :1788-+
[3]   Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour [J].
Bordiga, S ;
Lamberti, C ;
Ricchiardi, G ;
Regli, L ;
Bonino, F ;
Damin, A ;
Lillerud, KP ;
Bjorgen, M ;
Zecchina, A .
CHEMICAL COMMUNICATIONS, 2004, (20) :2300-2301
[4]   Enhanced Hydrogen Storage by Palladium Nanoparticles Fabricated in a Redox-Active Metal-Organic Framework [J].
Cheon, Young Eun ;
Suh, Myunghyun Paik .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (16) :2899-2903
[5]   Palladium Nanoparticles Supported on ZIF-8 As an Efficient Heterogeneous Catalyst for Aminocarbonylation [J].
Dang, Tuan T. ;
Zhu, Yinghuai ;
Ngiam, Joyce S. Y. ;
Ghosh, Subhash C. ;
Chen, Anqi ;
Seayad, Abdul M. .
ACS CATALYSIS, 2013, 3 (06) :1406-1410
[6]   Catalysis by metal nanoparticles embedded on metal-organic frameworks [J].
Dhakshinamoorthy, Amarajothi ;
Garcia, Hermenegildo .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (15) :5262-5284
[7]   Metal-organic frameworks as heterogeneous catalysts for oxidation reactions [J].
Dhakshinamoorthy, Amarajothi ;
Alvaro, Mercedes ;
Garcia, Hermenegildo .
CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (06) :856-867
[8]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[9]   Hybrid porous solids:: past, present, future [J].
Ferey, Gerard .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214
[10]   Catalytic properties of MIL-101 [J].
Henschel, Antje ;
Gedrich, Kristina ;
Kraehnert, Ralph ;
Kaskel, Stefan .
CHEMICAL COMMUNICATIONS, 2008, (35) :4192-4194
123