Polymer-anchored copper(II) complex: an efficient reusable catalyst for the synthesis of propargylamines

被引：17
作者：
Kodicherla, Balaswamy [1 ]
Perumgani, Pullaiah C. [1 ]
Mandapati, Mohan Rao [1 ]
机构：
[1] Indian Inst Chem Technol, I&PC Div, Hyderabad 500607, Andhra Pradesh, India
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2014年 / 28卷 / 10期
关键词：
polymer-anchored copper(II) catalyst; propargylamine; aldehyde; amine; alkyne; HIGHLY EFFICIENT; TERMINAL ALKYNES; MULTICOMPONENT REACTIONS; 3-COMPONENT SYNTHESIS; RECYCLABLE CATALYST; DIRECT-ADDITION; ALDEHYDE; AMINES; MILD; ALKYNYLATION;
D O I：
10.1002/aoc.3193
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new, heterogeneous, polymer-supported copper(II) complex was prepared and characterized using various techniques, including Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, atomic absorption spectroscopy and thermogravimetric analysis. This heterogeneous copper catalyst is efficient for the synthesis of propargylamines via a three-component coupling reaction of aldehydes, amines and alkynes. The effect of solvent on the coupling reactions was investigated. Further, the catalyst can be easily recovered quantitatively by simple filtration and reused for a minimum number of cycles without significant loss of its catalytic activity. Copyright (C) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码：756 / 759
页数：4
相关论文
共 50 条
  • [31] Copper nanoparticles supported on starch micro particles as a degradable heterogeneous catalyst for three-component coupling synthesis of propargylamines
    Gholinejad, Mohammad
    Saadati, Fariba
    Shaybanizadeh, Shahram
    Pullithadathil, Biji
    RSC ADVANCES, 2016, 6 (06) : 4983 - 4991
  • [32] Eco-friendly magnetic clinoptilolite containing Cu(0) nanoparticles (CuNPs/MZN): as a new efficient catalyst for the synthesis of propargylamines via A3 and KA2 coupling reactions
    Siuki, Mohammad Mehdi Khakzad
    Bakavoli, Mehdi
    Eshghi, Hossein
    APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (04)
  • [33] Ruthenium anchored on multi-walled carbon nanotubes: an efficient and reusable catalyst for the synthesis of xanthenes
    Tabatabaeian, Khalil
    Zanjanchi, Mohammad Ali
    Mamaghani, Manouchehr
    Dadashi, Ali
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (05) : 5049 - 5067
  • [34] Synthesis and characterization of a Cu(II) Schiff base complex immobilized on graphene oxide and its catalytic application in the green synthesis of propargylamines
    Kumari, Shweta
    Shekhar, Amiya
    Pathak, Devendra D.
    RSC ADVANCES, 2016, 6 (19) : 15340 - 15344
  • [35] Magnetic polyvinylpolypyrrolidone polymer composite-supported copper(I) catalyst: an efficient and easily reusable catalyst for sustainable synthesis of 1,2,3-triazoles in water
    Aflak, Noura
    Essebbar, Fatima-Ezzahraa
    Bahsis, Lahoucine
    Ben El Ayouchia, Hicham
    Anane, Hafid
    Julve, Miguel
    Stiriba, Salah-Eddine
    RSC SUSTAINABILITY, 2024, 2 (10): : 2949 - 2958
  • [36] Expeditious and highly efficient synthesis of propargylamines using a Pd-Cu nanowires catalyst under solvent-free conditions
    Yi, Rongnan
    Wang, Zheng-Jun
    Liang, Zhiwu
    Xiao, Min
    Xu, Xinhua
    Li, Ningbo
    APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (06)
  • [37] Melamine Trisulfonic Acid as a Highly Efficient and Reusable Catalyst for the Synthesis of β-Acetamido Ketones
    Zare, Abdolkarim
    E-JOURNAL OF CHEMISTRY, 2012, 9 (04) : 2322 - 2331
  • [38] Copper(II) chelate-bonded magnetite nanoparticles: A new magnetically retrievable catalyst for the synthesis of propargylamines
    Shouli, Atefeh
    Menati, Saeid
    Sayyahi, Soheil
    COMPTES RENDUS CHIMIE, 2017, 20 (07) : 765 - 772
  • [39] Copper (II)-immobilized on Starch-coated Nanomagnetite as an Efficient and Magnetically Recoverable Catalyst for the Synthesis of Propargylamines through One-pot A3 Coupling Reaction
    Tajbakhsh, Mahmood
    Mazhari, Fatemeh
    Mavvaji, Mohammad
    ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2023, 55 (03) : 251 - 264
  • [40] Highly Efficient and Reusable Polymer Supported Palladium Catalyst for Copper Free Sonogashira Reaction in Water
    Sruthi, Pambingal Rajan
    Nimmi, Puthan Purayil
    Babu, Sukumaran Santhosh
    Anas, Saithalavi
    CHEMISTRYSELECT, 2022, 7 (14):
12345