Polymer-anchored copper(II) complex: an efficient reusable catalyst for the synthesis of propargylamines

被引：17
|
作者：
Kodicherla, Balaswamy [1 ]
Perumgani, Pullaiah C. [1 ]
Mandapati, Mohan Rao [1 ]
机构：
[1] Indian Inst Chem Technol, I&PC Div, Hyderabad 500607, Andhra Pradesh, India
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2014年 / 28卷 / 10期
关键词：
polymer-anchored copper(II) catalyst; propargylamine; aldehyde; amine; alkyne; HIGHLY EFFICIENT; TERMINAL ALKYNES; MULTICOMPONENT REACTIONS; 3-COMPONENT SYNTHESIS; RECYCLABLE CATALYST; DIRECT-ADDITION; ALDEHYDE; AMINES; MILD; ALKYNYLATION;
D O I：
10.1002/aoc.3193
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new, heterogeneous, polymer-supported copper(II) complex was prepared and characterized using various techniques, including Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, atomic absorption spectroscopy and thermogravimetric analysis. This heterogeneous copper catalyst is efficient for the synthesis of propargylamines via a three-component coupling reaction of aldehydes, amines and alkynes. The effect of solvent on the coupling reactions was investigated. Further, the catalyst can be easily recovered quantitatively by simple filtration and reused for a minimum number of cycles without significant loss of its catalytic activity. Copyright (C) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码：756 / 759
页数：4
相关论文
共 50 条
  • [1] Functionalized Polystyrene Supported Copper(I) Complex as an Effective and Reusable Catalyst for Propargylamines Synthesis in Aqueous Medium
    Islam, Md. Mominul
    Roy, Anupam Singha
    Islam, Sk. Manirul
    CATALYSIS LETTERS, 2016, 146 (06) : 1128 - 1138
  • [2] Copper(I)-N2S2-salen type complex covalently anchored onto MCM-41 silica: an efficient and reusable catalyst for the A3-coupling reaction toward propargylamines
    Naeimi, Hossein
    Moradian, Mohsen
    APPLIED ORGANOMETALLIC CHEMISTRY, 2013, 27 (05) : 300 - 306
  • [3] Efficient Method for the Synthesis of Propargylamines Using a Biomaterial Containing Copper Nanoparticles as Impressive and Reusable Nanocatalyst
    Saadati, Fariba
    Gholinejad, Mohammad
    Janmohammadi, Hadiseh
    Shaybanizadeh, Shahram
    LETTERS IN ORGANIC CHEMISTRY, 2018, 15 (02) : 79 - 86
  • [4] A simple procedure for polymer-supported N-heterocyclic carbene silver complex via click chemistry: an efficient and recyclable catalyst for the one-pot synthesis of propargylamines
    He, Ying
    Lv, Mei-fang
    Cai, Chun
    DALTON TRANSACTIONS, 2012, 41 (40) : 12428 - 12433
  • [5] Polymer-anchored [Fe(III)Azo] complex: An efficient reusable catalyst for oxidative bromination and multi-components reaction for the synthesis of spiropiperidine derivatives
    Khatun, Resmin
    Biswas, Surajit
    Ghosh, Swarbhanu
    Islam, Sk. Manirul
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 858 : 37 - 46
  • [6] A Reusable Polymer-Anchored Palladium(II) Schiff Base Complex Catalyst for the Suzuki Cross-Coupling, Heck and Cyanation Reactions
    Islam, S. M.
    Mondal, P.
    Tuhina, K.
    Roy, A. S.
    Mondal, S.
    Hossain, D.
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2010, 20 (02) : 264 - 277
  • [7] Eggshell-supported-Cu(II) salophen complex: An efficient and green catalyst for synthesis of propargylamines under solvent-free conditions
    Bakherad, Mohammad
    Keivanloo, Ali
    Amin, Amir Hossein
    Doosti, Raheleh
    Hoseini, Ommolbanin
    IRANIAN JOURNAL OF CATALYSIS, 2016, 6 (04): : 325 - 332
  • [8] Copper nanoparticles decorated on boron nitride nanoflakes as an efficient catalyst for the synthesis of propargylamines under green conditions
    Piranloo, Fardin Ghasemy
    Abharian, Mahshid Kazemi
    Kavousi, Fatimah
    Luque, Rafael
    MOLECULAR CATALYSIS, 2022, 533
  • [9] A highly efficient polymer-anchored palladium(II) complex catalyst for hydrogenation, Heck cross-coupling and cyanation reactions
    Islam, S. M.
    Mondal, Paramita
    Tuhina, Kazi
    Roy, Anupam Singha
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2010, 85 (07) : 999 - 1010
  • [10] Magnetically separable Fe3O4 nanoparticles: an efficient catalyst for the synthesis of propargylamines
    Sreedhar, B.
    Kumar, A. Suresh
    Reddy, P. Surendra
    TETRAHEDRON LETTERS, 2010, 51 (14) : 1891 - 1895
12345