Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins

被引：7
|
作者：
Faraji, Laleh [1 ]
Samadi, Saadi [1 ]
Jadidi, Khosrow [1 ]
Notash, Behrouz [1 ]
机构：
[1] Shahid Beheshti Univ, Dept Chem, Gc Tehran 1983963113, Iran
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2014年 / 35卷 / 07期
关键词：
Chiral diamino alcohols; Chiral hydroxyldiamides; Asymmetric allylic oxidation; Small chiral libraries; Chiral pool amino acids; HIV PROTEASE; ENANTIOSELECTIVE ADDITION; AMINO-ACIDS; DIASTEREOSELECTIVE SYNTHESIS; STEREOCONTROLLED SYNTHESIS; SYMMETRICAL INHIBITORS; DIETHYLZINC; DERIVATIVES; ALDEHYDES; LIGANDS;
D O I：
10.5012/bkcs.2014.35.7.1989
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxykliamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
引用
收藏
页码：1989 / 1995
页数：7
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