Terpenoids from Guarea guidonia

被引:57
作者
Lago, JHG
Brochini, CB
Roque, NF
机构
[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil
[2] Univ Fed Bahia, Inst Quim, BR-40170290 Salvador, BA, Brazil
基金
巴西圣保罗研究基金会;
关键词
Guarea guidonia; Meliaceae; sesquiterpenes; triterpenes;
D O I
10.1016/S0031-9422(02)00089-4
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The volatile oil and the methanol extract from the leaves of Guarea guidonia, Meliaceae, were individually submitted to chromatographic separation. A sesquiterpene (2S*)-eudesma-5,7-dien-2-ol, together with six known ones, were isolated from the volatile oil. The methanolic extract afforded two known and two new triterpenes (23S*)-cycloart-24-ene-3beta,23-diol and (23R*)-cycloart-24-ene-3beta,23-diol, besides three known sesquiterpenes, one known diterpene and two steroids. Their structures were established on the basis of spectrocopic data, mainly by H-1 and C-13 NMR spectroscopic analyses. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:333 / 338
页数:6
相关论文
共 27 条
[1]   SESQUITERPENES FROM LIABUM-FLORIBUNDUM [J].
BOHLMANN, F ;
UMEMOTO, K ;
JAKUPOVIC, J ;
KING, RM ;
ROBINSON, H .
PHYTOCHEMISTRY, 1984, 23 (08) :1800-1802
[2]   Identification of components from volatile oils:: Spectroscopical analysis of sesquiterpenes mixtures. [J].
Brochini, CB ;
Núñez, CV ;
Moreira, IC ;
Roque, NF ;
Chaves, MH ;
Martins, D .
QUIMICA NOVA, 1999, 22 (01) :37-40
[3]   Two new cneorubin related diterpenes from the leaves of Guarea guidonia (Meliaceae) [J].
Brochini, CB ;
Roque, NF .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2000, 11 (04) :361-364
[4]  
CORREA M.P, 1978, DICIONARIO PLANTAS U, VII
[5]   TERPENOIDS FROM AGERATINA-SALTILLENSIS [J].
FANG, N ;
YU, SG ;
MABRY, TJ ;
ABBOUD, KA ;
SIMONSEN, SH .
PHYTOCHEMISTRY, 1988, 27 (10) :3187-3196
[6]  
Furlan M., 1993, Ecletica Quimica, V18, P113
[7]   Diterpenes from Guarea trichilioides [J].
Furlan, M ;
Lopes, MN ;
Fernandes, JB ;
Pirani, JR .
PHYTOCHEMISTRY, 1996, 41 (04) :1159-1161
[8]   CYCLOARTANE DERIVATIVES FROM GUAREA-TRICHILIOIDES [J].
FURLAN, M ;
ROQUE, NF ;
FILHO, WW .
PHYTOCHEMISTRY, 1993, 32 (06) :1519-1522
[9]   Sesquiterpenes, limonoid and coumarin from the wood bark of Guarea guidonia [J].
Garcez, FR ;
Nunez, CV ;
Garcez, WS ;
Almeida, RM ;
Roque, NF .
PLANTA MEDICA, 1998, 64 (01) :79-80
[10]  
Goodwin T.I., 1983, INTRO PLANT BIOCH