Fabrication of blue luminescent MoS2 quantum dots by wet grinding assisted co-solvent sonication

被引:63
作者
Ali, Junaid [1 ]
Siddiqui, Ghayas Uddin [1 ]
Choi, Kyung Hyun [1 ]
Jang, Yunseok [2 ]
Lee, Kangtaek [3 ]
机构
[1] Jeju Natl Univ, Dept Mech Engn, Jeju, South Korea
[2] Korea Inst Machinery & Mat, Dept Printed Elect, Taejon, South Korea
[3] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词
2D materials; Luminescence; MoS2; Quantum dots; Synthesis; EXFOLIATED MOS2; GRAPHENE; NANOSHEETS; ENERGY; PHOTOLUMINESCENCE; DISPERSIONS; EFFICIENT;
D O I
10.1016/j.jlumin.2015.09.028
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Molybdenum disulfide (MoS2) belongs to transition-metal dichalcogenides (TMDs) family and has vital position among 2D materials. Here, an efficient strategy for the synthesis of zero-dimensional MoS2 quantum dots (QDs) has been represented. This strategy consists of wet grinding of pristine MoS2 in N-methyl-2-pyrrolidone (NMP) followed by sonication in NMP and 1,2-dichlorobenzene (o-DCB). The efficacy of this approach to synthesize MoS2 QDs has been reported by analyzing the as synthesized MoS2 QDs by different characterization techniques such as high resolution transmission electron microscopy, energy dispersive x-ray spectroscopy, Raman spectroscopy, photoluminescence spectroscopy, Fourier transform infrared spectroscopy and UV-vis spectroscopy. The concentration (yield) of as synthesized MoS2 QDs was found to be 7 mg mL(-1). Most of the MoS2 QDs were measured around 2-5 nm in size. The as synthesized MoS2 QDs showed distinct blue luminescence upon UV excitation. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:342 / 347
页数:6
相关论文
共 45 条
[41]   Graphene-based Schottky junction solar cells [J].
Ye, Yu ;
Dai, Lun .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (46) :24224-24229
[42]   Multiflake Thin Film Electronic Devices of Solution Processed 2D MoS2 Enabled by Sonopolymer Assisted Exfoliation and Surface Modification [J].
Yu, Xiaoyun ;
Prevot, Mathieu S. ;
Sivula, Kevin .
CHEMISTRY OF MATERIALS, 2014, 26 (20) :5892-5899
[43]   High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide [J].
Zheng, Jian ;
Zhang, Han ;
Dong, Shaohua ;
Liu, Yanpeng ;
Nai, Chang Tai ;
Shin, Hyeon Suk ;
Jeong, Hu Young ;
Liu, Bo ;
Loh, Kian Ping .
NATURE COMMUNICATIONS, 2014, 5
[44]   A Mixed-Solvent Strategy for Efficient Exfoliation of Inorganic Graphene Analogues [J].
Zhou, Kai-Ge ;
Mao, Nan-Nan ;
Wang, Hang-Xing ;
Peng, Yong ;
Zhang, Hao-Li .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (46) :10839-10842
[45]   Single-Layer MoS2-Based Nanoprobes for Homogeneous Detection of Biomolecules [J].
Zhu, Changfeng ;
Zeng, Zhiyuan ;
Li, Hai ;
Li, Fan ;
Fan, Chunhai ;
Zhang, Hua .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (16) :5998-6001