Detection of Perchlorate and the Soluble Chemistry of Martian Soil at the Phoenix Lander Site

被引:847
作者
Hecht, M. H. [1 ]
Kounaves, S. P. [2 ]
Quinn, R. C. [3 ]
West, S. J. [4 ]
Young, S. M. M. [2 ]
Ming, D. W. [5 ]
Catling, D. C. [6 ,7 ]
Clark, B. C. [8 ]
Boynton, W. V. [9 ]
Hoffman, J. [10 ]
DeFlores, L. P. [1 ]
Gospodinova, K. [2 ]
Kapit, J. [2 ]
Smith, P. H. [9 ]
机构
[1] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA
[2] Tufts Univ, Dept Chem, Medford, MA 02155 USA
[3] NASA, Ames Res Ctr, SETI Inst, Moffett Field, CA 94035 USA
[4] Invensys Proc Syst, Foxboro, MA 02035 USA
[5] NASA, Lyndon B Johnson Space Ctr, Astromat Res & Explorat Sci Directorate, Houston, TX 77058 USA
[6] Univ Bristol, Dept Earth Sci, Bristol BS8 1RJ, Avon, England
[7] Univ Washington, Dept Earth & Space Sci, Seattle, WA 98195 USA
[8] Space Sci Inst, Boulder, CO 80301 USA
[9] Univ Arizona, Lunar & Planetary Lab, Tucson, AZ 85721 USA
[10] Univ Texas Dallas, Dept Phys, Richardson, TX 75080 USA
关键词
CHEMICAL-COMPOSITION; MARS; SURFACE; SPECTROMETER; ORIGIN; ROCKS;
D O I
10.1126/science.1172466
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The Wet Chemistry Laboratory on the Phoenix Mars Lander performed aqueous chemical analyses of martian soil from the polygon-patterned northern plains of the Vastitas Borealis. The solutions contained similar to 10 mM of dissolved salts with 0.4 to 0.6% perchlorate (ClO4) by mass leached from each sample. The remaining anions included small concentrations of chloride, bicarbonate, and possibly sulfate. Cations were dominated by Mg2+ and Na+, with small contributions from K+ and Ca2+. A moderately alkaline pH of 7.7 +/- 0.5 was measured, consistent with a carbonate-buffered solution. Samples analyzed from the surface and the excavated boundary of the similar to 5-centimeter-deep ice table showed no significant difference in soluble chemistry.
引用
收藏
页码:64 / 67
页数:4
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