Elemental fluorine .7. New oxidation methodology

被引：7

作者：

Chambers, RD

Hutchinson, J

Sandford, G

Shah, A

Vaughan, JFS

机构：

[1] Department of Chemistry, University of Durham, Durham DH1 3LE, South Road

来源：

TETRAHEDRON | 1997年 / 53卷 / 46期

关键词：

D O I：

10.1016/S0040-4020(97)10043-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of fluorine with water in the presence of acids provides new oxidants for 'in-situ' oxidation of ketones. Direct reaction of fluorine with anhydrous alcohols and 1,2-diols provides simple methodology for oxidation to corresponding secondary ketones or alpha-hydroxy ketones. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：15833 / 15842

页数：10

相关论文

共 15 条

[1] SYNTHESIS, CHARACTERIZATION, AND REACTION CHEMISTRY OF TERT-BUTYL HYPOFLUORITE [J].

APPELMAN, EH ;

FRENCH, D ;

MISHANI, E ;

ROZEN, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (04) :1379-1382

[2]

BARRIERE JC, 1996, Patent No. 04299

[3]

CARRUTHERS W, 1989, SOME MODERN METHODS

[4] Elemental fluorine .5. Reactions of 1,3-dithiolanes and thioglycosides with fluorine-iodine mixtures [J].

Chambers, RD ;

Sandford, G ;

Sparrowhawk, ME ;

Atherton, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (16) :1941-1944

[5] ELECTROPHILIC FLUORINATION USING ELEMENTAL FLUORINE [J].

CHAMBERS, RD ;

SKINNER, CJ ;

THOMSON, J ;

HUTCHINSON, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (01) :17-17

[6] Elemental fluorine .6. Fluorination of cyclic 1,3-diketones and related compounds [J].

Chambers, RD ;

Hutchinson, J ;

Batsanov, AS ;

Lehmann, CW ;

Naumov, DY .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (18) :2271-2275

[7] Elemental fluorine .4. Use of elemental fluorine for the halogenation of aromatics [J].

Chambers, RD ;

Skinner, CJ ;

Atherton, MJ ;

Moilliet, JS .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (14) :1659-1664

[8] Elemental fluorine .1. Synthesis of fluoroaromatic compounds [J].

Chambers, RD ;

Skinner, CJ ;

Hutchinson, J ;

Thomson, J .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (07) :605-609

[9] A STUDY OF THE REGIOSELECTIVITY OF OXYGEN INSERTION IN THE BAEYER-VILLIGER OXIDATION OF BICYCLO[2.2.1]HEPTAN-2-ONES [J].

HAMLEY, P ;

HOLMES, AB ;

MARSHALL, DR ;

MACKINNON, JWM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (08) :1793-1802

[10] BAEYER-VILLIGER OXIDATION WITH ME3SIOOSIME3 UNDER ASSISTANCE OF SNCL4 OR BF3.OET2 [J].

MATSUBARA, S ;

TAKAI, K ;

NOZAKI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (07) :2029-2032