Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates: an interesting photoinduced coloration phenomenon of mixed-metal clusters involving energy transfer from rare-earth fluorescence

被引：13

作者：

Liu Li ^{[1
]}

Li HongMei ^{[1
]}

Dai JingCao ^{[1
]}

机构：

[1] Huaqiao Univ, Inst Mat Phys Chem, Xiamen 361021, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2014年 / 57卷 / 06期

基金：

中国国家自然科学基金;

关键词：

lanthanide-decorated polyoxomolybdates; photocoloration; solar-furnace; photoactivation; energy transfer; ORGANIC SUBSTRATE; CHARGE-TRANSFER; POLYOXOMETALATE; PHOTOCHROMISM; NANOPARTICLE; COMPOSITE; CRYSTAL; CENTERS; COMPLEX;

D O I：

10.1007/s11426-014-5081-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ce/Sm ions are covalently grafted to a Keggin polyoxomolybdate cluster [PMo12O40](3-) to yield interesting fluorescent-photodarkening molecular systems. Their photoresponce processes are observed to be activated via energy transfer from luminescent fragments to photocoloration components.

引用

页码：918 / 922

页数：5

共 2 条

[1] Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates: an interesting photoinduced coloration phenomenon of mixed-metal clusters involving energy transfer from rare-earth fluorescence
Li Liu
HongMei Li
JingCao Dai
Science China Chemistry, 2014, 57 : 918 - 922
[2] Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates:an interesting photoinduced coloration phenomenon of mixed- metal clusters involving energy transfer from rare-earth fluorescence
LIU Li
LI HongMei
DAI JingCao
Science China(Chemistry), 2014, (06) : 918 - 930

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