Fabrication of Electrically Conductive Metal Patterns at the Surface of Polymer Films by Microplasma-Based Direct Writing

被引：36

作者：

Ghosh, Souvik ^{[1
]}

Yang, Rui ^{[2
]}

Kaumeyer, Michelle ^{[2
]}

Zorman, Christian A. ^{[2
]}

Rowan, Stuart J. ^{[3
]}

Feng, Philip X. -L. ^{[2
]}

Sankaran, R. Mohan ^{[1
]}

机构：

[1] Case Western Reserve Univ, Dept Chem Engn, Cleveland, OH 44106 USA

[2] Case Western Reserve Univ, Dept Elect Engn & Comp Sci, Cleveland, OH 44106 USA

[3] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA

来源：

ACS APPLIED MATERIALS & INTERFACES | 2014年 / 6卷 / 05期

基金：

美国国家科学基金会;

关键词：

microplasma; direct write; electrodiffusion; printed electronics; flexible electronics; sheet resistance; ROLL-TO-ROLL; POLY(ACRYLIC ACID); NANOPARTICLES; FEATURES; INKJET;

D O I：

10.1021/am406005a

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We describe a direct-write process for producing electrically conductive metal patterns at the surface of polymers. Thin films of poly(acrylic acid) (PAA) loaded with Ag ions are reduced by a scanning, atmospheric-pressure microplasma to form crystalline Ag features with a line width of 300 mu m. Materials analysis reveals that the metallization occurs in a thin layer of similar to 5 mu m near the film surface, suggesting that, the Ag ions diffuse to the surface. Sheet resistances of 1-10 Omega/sq are obtained independent of film thickness and Ag volume concentration, which is desirable for producing surface conductivity on polymers while minimizing metal loading.

引用

页码：3099 / 3104

页数：6

共 31 条

[11]

Le W., 2011, J APPL POLYM SCI, V124, P1912

[12] TRANSPORT OF SILVER UNDER INFLUENCE OF AN ELECTRIC-FIELD IN GLASSY AS2SE3 [J].

LEBEDEV, EA ;

SUPTITZ, P ;

WILLERT, I .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1975, 28 (02) :461-466

[13] In Situ Formation of Metal Nanoparticle Composites via "Soft" Plasma Electrochemical Reduction of Metallosupramolecular Polymer Films [J].

Lee, Seung Whan ;

Kumpfer, Justin R. ;

Lin, Pin Ann ;

Li, Guodong ;

Gao, Xuan P. A. ;

Rowan, Stuart J. ;

Sankaran, R. Mohan .

MACROMOLECULES, 2012, 45 (20) :8201-8210

[14] Direct Writing Patterns for Electroless Plated Copper Thin Film on Plastic Substrates [J].

Liao, Ying-Chih ;

Kao, Zhen-Kai .

ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (10) :5109-5113

[15] Optimization of Aerosol Jet Printing for High-Resolution, High-Aspect Ratio Silver Lines [J].

Mahajan, Ankit ;

Frisbie, C. Daniel ;

Francis, Lorraine F. .

ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (11) :4856-4864

[16] Recent progress in multiphoton microfabrication [J].

Maruo, Shoji ;

Fourkas, John T. .

LASER & PHOTONICS REVIEWS, 2008, 2 (1-2) :100-111

[17] Photo-Roll Lithography (PRL) for Continuous and Scalable Patterning with Application in Flexible Electronics [J].

Ok, Jong G. ;

Kwak, Moon Kyu ;

Huard, Chad M. ;

Youn, Hong Seok ;

Guo, L. Jay .

ADVANCED MATERIALS, 2013, 25 (45) :6554-6561

[18] Printed electronics: the challenges involved in printing devices, interconnects, and contacts based on inorganic materials [J].

Perelaer, Jolke ;

Smith, Patrick J. ;

Mager, Dario ;

Soltman, Daniel ;

Volkman, Steven K. ;

Subramanian, Vivek ;

Korvink, Jan G. ;

Schubert, Ulrich S. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (39) :8446-8453

[19] Metal Anion-Alkyl Ammonium Complexes as Direct Write Precursors to Produce Nanopatterns of Metals, Nitrides, Oxides, Sulfides, And Alloys [J].

Radha, B. ;

Kiruthika, S. ;

Kulkarni, G. U. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (32) :12706-12713

[20] Plasma-liquid electrochemistry: Rapid synthesis of colloidal metal nanoparticles by microplasma reduction of aqueous cations [J].

Richmonds, Carolyn ;

Sankaran, R. Mohan .

APPLIED PHYSICS LETTERS, 2008, 93 (13)

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