Synthesis and characterization of various zeolites and study of dynamic adsorption of dimethyl methyl phosphate over them

被引：30
作者：
Khanday, Waheed Ahmad [1 ]
Majid, Sheikh Abdul [1 ]
Shekar, S. Chandra [2 ]
Tomar, Radha [1 ]
机构：
[1] Jiwaji Univ, SOS Chem, Gwalior 474011, MP, India
[2] Def R&D Estab, Gwalior 474002, MP, India
来源：
MATERIALS RESEARCH BULLETIN | 2013年 / 48卷 / 11期
关键词：
Microporous materials; X-ray diffraction; Electron microscopy; Surface properties; METHYLPHOSPHONATE DMMP; DECOMPOSITION; SIMULANTS; SENSORS; SURFACE;
D O I：
10.1016/j.materresbull.2013.08.003
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Zeolite-A, MCM-22, Zeolite-X and Erionite were synthesized successfully under hydrothermal conditions and were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Brunauer-Emmett-Teller (BET) surface area analysis and thermal programmed desorption (TPD). Dynamic adsorption of dimethyl methyl phosphate (DMMP) was carried out on these zeolites. Zeolite-X having high surface area among all four zeolites shows highest adsorption capacity followed by Erionite and MCM-22 where as Zeolite-A shows the least. For all zeolites adsorption was found to be high initially and it then decreases with increase in injected volume. Then desorption pattern was analyzed which shows two types of peaks, sharp peak representing desorption of physisorbed DMMP and a broad peak representing desorption of strongly chemisorbed DMMP. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4679 / 4686
页数：8
相关论文
共 14 条
  • [1] A review of chemical warfare agent simulants for the study of environmental behavior
    Bartelt-Hunt, Shannon L.
    Knappe, Detlef R. U.
    Barlaz, Morton A.
    [J]. CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2008, 38 (02) : 112 - 136
  • [2] Detection of dimethyl methylphosphonate (DMMP) by tin dioxide-based gas sensor: Response curve and understanding of the reactional mechanism
    Brunol, E.
    Berger, F.
    Fromm, A.
    Planade, R.
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2006, 120 (01) : 35 - 41
  • [3] Thermocatalytic decomposition of dimethyl methylphosphonate on activated carbon
    Cao, LX
    Suib, SL
    Tang, X
    Satyapal, S
    [J]. JOURNAL OF CATALYSIS, 2001, 197 (02) : 236 - 243
  • [4] Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts
    Comini, E
    Faglia, G
    Sberveglieri, G
    Pan, ZW
    Wang, ZL
    [J]. APPLIED PHYSICS LETTERS, 2002, 81 (10) : 1869 - 1871
  • [5] SURFACE-CHEMISTRY OF ORGANO-PHOSPHORUS COMPOUNDS
    EKERDT, JG
    KLABUNDE, KJ
    SHAPLEY, JR
    WHITE, JM
    YATES, JT
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (22) : 6182 - 6188
  • [6] An infrared study of adsorbed organophosphonates on silica: A prefiltering strategy for the detection of nerve agents on metal oxide sensors
    Kanan, SM
    Tripp, CP
    [J]. LANGMUIR, 2001, 17 (07) : 2213 - 2218
  • [7] Study of sorption of Pb2+, Cd2+, Zn2+ and Cu2+ from wastewater on synthetic analogues of clintonite
    Khanday, W. A.
    Singh, S. K.
    Bhaudoriya, J.
    Majid, S. A.
    Tomar, S. S.
    Tomar, Radha
    [J]. COLLOID JOURNAL, 2012, 74 (05) : 573 - 581
  • [8] Environmental syntheses of nanosized zeolites with high yield and monomodal particle size distribution
    Larlus, O.
    Mintova, S.
    Bein, T.
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 96 (1-3) : 405 - 412
  • [9] Comparing synthesis routes to nano-crystalline zeolite ZSM-5
    Reding, G
    Mäurer, T
    Kraushaar-Czarnetzki, B
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 57 (01) : 83 - 92
  • [10] Endocrine disrupting chemicals in indoor and outdoor air
    Rudel, Ruthann A.
    Perovich, Laura J.
    [J]. ATMOSPHERIC ENVIRONMENT, 2009, 43 (01) : 170 - 181
12