The reaction of oxygen with CO complexes on calcium oxide and magnesium oxide

被引：2

作者：

Bailes, M ^{[1
]}

Stone, FS ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TOPICS IN CATALYSIS | 2000年 / 11卷 / 1-4期

关键词：

CaO; MgO; carbon monoxide complexes; oxidation; adsorption calorimetry;

D O I：

10.1023/A:1027279326576

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The heat evolved during the adsorption and oligomerization of CO on outgassed CaO and MgO has been determined with a heat-flow calorimeter. The chemisorbed complexes formed include highly-conjugated (CO)(n)(2-) anions which impart colour to the oxides. The reaction of these complexes with oxygen has been quantified calorimetrically and correlated with changes observed spectroscopically.

引用

收藏

页码：213 / 222

页数：10

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