Mechanistic Surprises in the Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes

被引：215

作者：

Weber, Dieter ^{[1
]}

Tarselli, Michael A. ^{[1
]}

Gagne, Michel R. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 31期

关键词：

allenes; gold; homogeneous catalysis; hydroarylation; reaction mechanisms; GOLD-CATALYZED CYCLIZATIONS; STRUCTURAL-CHARACTERIZATION; SUBSTITUTED TETRAHYDRONAPHTHALENES; BOND FORMATION; COMPLEXES; CYCLOISOMERIZATION; ACTIVATION; REACTIVITY; CHEMISTRY; EFFICIENT;

D O I：

10.1002/anie.200902049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two for the show: Mechanistic studies on the cyclization of allenic arenes indicated that the catalyst rests at a dinuclear bridging vinyl structure, which was isolated and its reactivity examined. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5733 / 5736

页数：4

共 53 条

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