Metal-impregnated zeolite Y as efficient catalyst for the direct carbonation of glycerol with CO2

被引：43

作者：

Ozorio, Leonardo P. ^{[1
]}

Pianzolli, Rafael ^{[2
]}

Machado, Luciana da Cruz ^{[1
]}

Miranda, Jussara L. ^{[2
]}

Turci, Cassia C. ^{[2
]}

Guerra, Antonio C. O. ^{[2
]}

Falabella Souza-Aguiar, E. ^{[1
,3
]}

Mota, Claudio J. A. ^{[1
,2
,4
]}

机构：

[1] Univ Fed Rio de Janeiro, Escola Quim, BR-21941909 Rio De Janeiro, Brazil

[2] Univ Fed Rio de Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, Brazil

[3] Cenpes, Petrobras, BR-21941915 Rio De Janeiro, Brazil

[4] Univ Fed Rio de Janeiro, INCT Energia & Ambiente, BR-21941909 Rio De Janeiro, Brazil

来源：

APPLIED CATALYSIS A-GENERAL | 2015年 / 504卷

关键词：

Glycerol; CO2; Glycerol carbonate; Zeolite; Metal oxide; DIMETHYL CARBONATE; SUPERCRITICAL CO2; DIOXIDE CAPTURE; CONVERSION; CHEMICALS; METHANOL; FUELS; TECHNOLOGY; FEEDSTOCK;

D O I：

10.1016/j.apcata.2014.12.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal-impregnated zeolite Y catalysts were prepared by treatment of a NaY zeolite with an aqueous solution of AgNO3, Zn(NO3)(2) and SnCl2, followed by water evaporation. The materials were then calcined in air at 450 degrees C and evaluated in the reaction of CO2 with glycerol at 180 degrees C for 3 h at 100 Bar. The parent NaY zeolite was inactive under these conditions, but the metal-impregnated zeolites, as well as the calcined salt precursors, showed yields of glycerol carbonate up to 5.8%. The TON of the zeolite catalysts were significantly higher than that of the calcined salts, suggesting the formation of a highly active metal oxide phase at the external surface of the zeolite. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：187 / 191

页数：5

共 39 条

[31] Synthesis of glycerol carbonate by direct carbonatation of glycerol in supercritical CO2 in the presence of zeolites and ion exchange resins
Vieville, C
Yoo, JW
Pelet, S
Mouloungui, Z
[J]. CATALYSIS LETTERS, 1998, 56 (04) : 245 - 247
[32] Wang L., 2011, CATAL COMMUN, V131, P175
[33] Recent advances in catalytic hydrogenation of carbon dioxide
Wang, Wei
Wang, Shengping
Ma, Xinbin
Gong, Jinlong
[J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) : 3703 - 3727
[34] A review on carbon dioxide capture and storage technology using coal fly ash
Wee, Jung-Ho
[J]. APPLIED ENERGY, 2013, 106 : 143 - 151
[35] Efficient and Clean Photoreduction of CO2 to CO by Enzyme-Modified TiO2 Nanoparticles Using Visible Light
Woolerton, Thomas W.
Sheard, Sally
Reisner, Erwin
Pierce, Elizabeth
Ragsdale, Stephen W.
Armstrong, Fraser A.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (07) : 2132 - +
[36] Yoo JW, 2003, STUD SURF SCI CATAL, V146, P757
[37] Photocatalytic Conversion of Carbon Dioxide with Water into Methane: Platinum and Copper(I) Oxide Co-catalysts with a Core-Shell Structure
Zhai, Qingge
Xie, Shunji
Fan, Wenqing
Zhang, Qinghong
Wang, Yu
Deng, Weiping
Wang, Ye
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (22) : 5776 - 5779
[38] RETRACTED: Commodity Chemicals Derived from Glycerol, an Important Biorefinery Feedstock (Retracted Article. See vol 110, pg 1807, 2010)
Zheng, Yuguo
Chen, Xiaolong
Shen, Yinchu
[J]. CHEMICAL REVIEWS, 2008, 108 (12) : 5253 - 5277
[39] Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals
Zhou, Chun-Hui
Beltramini, Jorge N.
Fan, Yong-Xian
Lu, G. Q.
[J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (03) : 527 - 549

← 1 2 3 4 →