Hydrothermal preparation of CoO/Ti3C2 composite material for lithium-ion batteries with enhanced electrochemical performance

被引:49
作者
Li, Xuelin [1 ]
Zhu, Jianfeng [1 ]
Fang, Yuan [1 ]
Lv, Wenjing [1 ]
Wang, Fen [1 ]
Liu, Yi [1 ]
Liu, Hui [1 ]
机构
[1] Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Xian 710021, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
CoO/Ti3C2; Hydrothermal; Lithium-ion batteries; Electrical properties; ANODE MATERIAL; ELECTRODE MATERIALS; TITANIUM CARBIDE; HIGH-CAPACITY; STORAGE; MXENE; METAL; NANOCOMPOSITES; CARBON; TI3C2;
D O I
10.1016/j.jelechem.2018.03.031
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The CoO/Ti3C2 composite is prepared via a facile hydrothermal route followed by calcination, of which the morphology and the microstructure are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). CoO nanoparticles with the diameter of 10-20 nm are uniformly coated on the surface of Ti3C2 nanosheets, which increases the surface areas and prevents the aggregation of CoO. In addition, the CoO/Ti3C2 composite as an anode material for lithium-ion batteries (LIBs) demonstrates a higher initial discharge capacity of 1389 mAh g(-1) with a columbic efficiency of 61% at 100 mAh g(-1). The reversible capacity can remain about 313 mAh g(-1) after 100 cycles, which is much higher than that of the pure Ti3C2. The present results indicate that CoO/Ti3C2 composite has a potential application in the anode of LIB.
引用
收藏
页码:1 / 8
页数:8
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