Nickel-catalyzed cross-coupling of diarylamines with haloarenes

被引：57

作者：

Gao, Cai-Yan ^{[1
,2
]}

Cao, Xingbo ^{[1
,2
]}

Yang, Lian-Ming ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, New Mat Lab, BNLMS, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2009年 / 7卷 / 19期

基金：

中国国家自然科学基金;

关键词：

ARYL CHLORIDES; AMINATION; ARYLATION; NITROGEN; COMPLEXES; AMINES; WELL;

D O I：

10.1039/b911286c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cross-coupling reaction of diarylamines with aryl bromides/iodides can be effected by the Ni(II)-(sigma-aryl) complex/PPh3/NaH system, and a preliminary investigation was conducted into the mechanism of this reaction.

引用

页码：3922 / 3925

页数：4

共 34 条

[1] An improved method for the palladium-catalyzed amination of aryl iodides [J].

Ali, MH ;

Buchwald, SL .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (08) :2560-2565

[2]

Brandsma L., 1998, SPRINGER LAB, P15

[3] Nickel-catalysed couplings of aryl chlorides with secondary amines and piperazines [J].

Brenner, E ;

Schneider, R ;

Fort, Y .

TETRAHEDRON, 1999, 55 (44) :12829-12842

[4] New efficient nickey(0) catalysed amination of aryl chlorides [J].

Brenner, E ;

Fort, Y .

TETRAHEDRON LETTERS, 1998, 39 (30) :5359-5362

[5]

CASSAR L, 1974, ADV CHEM SER, P252

[6] Arylation of diarylamines catalyzed by Ni(II)-PPh3 system [J].

Chen, C ;

Yang, LM .

ORGANIC LETTERS, 2005, 7 (11) :2209-2211

[7] Ni(II)-(σ-Aryl) complex:: A facile, efficient catalyst for nickel-catalyzed carbon-nitrogen coupling reactions [J].

Chen, Chen ;

Yang, Lian-Ming .

JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (16) :6324-6327

[8] Efficient synthesis of triarylamines catalyzed by palladium/N-heterocyclic carbene [J].

Chen, Chen ;

Li, Ying-Feng ;

Yang, Lian-Ming .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 269 (1-2) :158-162

[9] ELECTRIC DIPOLE MOMENTS AND MOLECULAR CONFORMATIONS OF AROMATIC AMINES, PHOSPHITES, AND PHOSPHATES [J].

CUMPER, CWN ;

THURSTON, AP .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (03) :422-&

[10] Nickel (0)/dihydroimidazol-2-ylidene complex catalyzed coupling of aryl chlorides and amines [J].

Desmarets, C ;

Schneider, R ;

Fort, Y .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (09) :3029-3036

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