Synthesis and characterization of a platinum(II) complex with N-acetyl-L-cysteine

被引：13

作者：

Corbi, P. P. ^{[1
,2
]}

Cagnin, F. ^{[2
]}

Massabni, A. C. ^{[2
]}

机构：

[1] Ctr Univ Araraquara UNIARA, Associacao Sao Bento Ensino, Dept Ciencias Biol & Saude, BR-14801320 Araraquara, SP, Brazil

[2] UNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 17期

基金：

巴西圣保罗研究基金会;

关键词：

N-Acetyl-L-cysteine; Platinum(II); Solid-state NMR; Infrared spectroscopy; Thermal analysis; PALLADIUM(II) COMPLEX; AMINO-ACIDS; CRYSTAL-STRUCTURE; ACETYLCYSTEINE; DEOXYALLIIN; MECHANISMS; REACTIVITY; CHLORIDE; LIGANDS; CATION;

D O I：

10.1080/00958970902942974

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and spectroscopic studies in the solid-state of a platinum(II) complex with N-acetyl-L-cysteine are described. Elemental analyses are consistent with composition Pt2(C5H8NO3S)4 center dot 3H2O. Solid-state 13C NMR, infrared, and U-Vis spectroscopic results are consistent with coordination of the ligand to platinum(II) through sulfur. Thermal analyses confirmed water in the complex composition. Final residue of the thermal treatment was identified by powder X-ray diffractometry as metallic platinum.

引用

页码：2764 / 2771

页数：8

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