The synthesis of a novel graphene-based inorganic-organic hybrid flame retardant and its application in epoxy resin

被引:159
作者
Wang, Zehao [1 ]
Wei, Ping [1 ]
Qian, Yong [1 ]
Liu, Jiping [2 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
[2] Beijing Inst Technol, Natl Lab Flame Retardant Mat, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
Polymer-matrix composites (PMCs); Hybrid; Thermal analysis; Thermosetting resin; THERMAL-STABILITY; GRAPHITE OXIDE; PHOSPHORUS; NANOCOMPOSITES; SILICON; FUNCTIONALIZATION; DEGRADATION; COMPOSITES; RESISTANCE; REDUCTION;
D O I
10.1016/j.compositesb.2013.12.033
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, a novel graphene-based inorganic organic hybrid flame retardant (GFR) was prepared via sal gel reaction of FGO and phenyl-bis-(triethoxysilylpropyl) phosphamide (PBTP) and characterized by FT-IR, XPS, XRD, TGA and AFM. The influence of the GFR on the thermal stability and flame retardance of epoxy resin composites were characterized by TGA, LOI as well as micro-cone, which indicated that GFR brought a good effect in enhancing the residual char and flame retardance of epoxy composites. The dynamic mechanical properties and electrical properties of EP composites were also analyzed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:341 / 349
页数:9
相关论文
共 32 条
  • [21] Phosphonium-modified layered silicate epoxy resins nanocomposites and their combinations with ATH and organo-phosphorus fire retardants
    Schartel, B
    Knoll, U
    Hartwig, A
    Pütz, D
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2006, 17 (04) : 281 - 293
  • [22] Gemini surfactant assisted synthesis of two-dimensional metal nanoparticles/graphene composites
    Song, Chunpeng
    Wu, Dongqing
    Zhang, Fan
    Liu, Ping
    Lu, Qinghua
    Feng, Xinliang
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (15) : 2119 - 2121
  • [23] Novel Spirocyclic Phosphazene-Based Epoxy Resin for Halogen-Free Fire Resistance: Synthesis, Curing Behaviors, and Flammability Characteristics
    Sun, Jian
    Wang, Xiaodong
    Wu, Dezhen
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (08) : 4047 - 4061
  • [24] Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst
    Sun, Yiqing
    Li, Chun
    Xu, Yuxi
    Bai, Hua
    Yao, Zhiyi
    Shi, Gaoquan
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (26) : 4740 - 4742
  • [25] Effect of silica content on thermal stability of fumed silica/epoxy composites
    Tarrio-Saaavedra, J.
    Lopez-Beceiro, J.
    Naya, S.
    Artiaga, R.
    [J]. POLYMER DEGRADATION AND STABILITY, 2008, 93 (12) : 2133 - 2137
  • [26] Thermal conductivity and structure of non-covalent functionalized graphene/epoxy composites
    Teng, Chih-Chun
    Ma, Chen-Chi M.
    Lu, Chu-Hua
    Yang, Shin-Yi
    Lee, Shie-Heng
    Hsiao, Min-Chien
    Yen, Ming-Yu
    Chiou, Kuo-Chan
    Lee, Tzong-Ming
    [J]. CARBON, 2011, 49 (15) : 5107 - 5116
  • [27] Simultaneous reduction and surface functionalization of graphene oxide with POSS for reducing fire hazards in epoxy composites
    Wang, Xin
    Song, Lei
    Yang, Hongyu
    Xing, Weiyi
    Kandola, Baljinder
    Hua, Yuan
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (41) : 22037 - 22043
  • [28] Graphene oxide/polybenzimidazole composites fabricated by a solvent-exchange method
    Wang, Yan
    Shi, Zixing
    Fang, Jianhua
    Xu, Hongjie
    Yin, Jie
    [J]. CARBON, 2011, 49 (04) : 1199 - 1207
  • [29] Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement
    Yang, Huafeng
    Li, Fenghua
    Shan, Changsheng
    Han, Dongxue
    Zhang, Qixian
    Niu, Li
    Ivaska, Ari
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (26) : 4632 - 4638
  • [30] Green synthesis of graphene oxide sheets decorated by silver nanoprisms and their anti-bacterial properties
    Zhang, Danhui
    Liu, Xiaoheng
    Wang, Xin
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 2011, 105 (09) : 1181 - 1186