The synthesis of a novel graphene-based inorganic-organic hybrid flame retardant and its application in epoxy resin

被引:159
作者
Wang, Zehao [1 ]
Wei, Ping [1 ]
Qian, Yong [1 ]
Liu, Jiping [2 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
[2] Beijing Inst Technol, Natl Lab Flame Retardant Mat, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
Polymer-matrix composites (PMCs); Hybrid; Thermal analysis; Thermosetting resin; THERMAL-STABILITY; GRAPHITE OXIDE; PHOSPHORUS; NANOCOMPOSITES; SILICON; FUNCTIONALIZATION; DEGRADATION; COMPOSITES; RESISTANCE; REDUCTION;
D O I
10.1016/j.compositesb.2013.12.033
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, a novel graphene-based inorganic organic hybrid flame retardant (GFR) was prepared via sal gel reaction of FGO and phenyl-bis-(triethoxysilylpropyl) phosphamide (PBTP) and characterized by FT-IR, XPS, XRD, TGA and AFM. The influence of the GFR on the thermal stability and flame retardance of epoxy resin composites were characterized by TGA, LOI as well as micro-cone, which indicated that GFR brought a good effect in enhancing the residual char and flame retardance of epoxy composites. The dynamic mechanical properties and electrical properties of EP composites were also analyzed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:341 / 349
页数:9
相关论文
共 32 条
  • [1] In situ preparation of functionalized graphene oxide/epoxy nanocomposites with effective reinforcements
    Bao, Chenlu
    Guo, Yuqiang
    Song, Lei
    Kan, Yongchun
    Qian, Xiaodong
    Hu, Yuan
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (35) : 13290 - 13298
  • [2] Synthesis, characterization and properties of novel self-extinguishing organic-inorganic nanocomposites containing nitrogen, silicon and phosphorus via sol-gel method
    Chiang, Chin-Lung
    Chang, Ri-Cheng
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (14) : 2849 - 2857
  • [3] Thermal stability and degradation kinetics of novel organic/inorganic epoxy hybrid containing nitrogen/silicon/phosphorus by sol-gel method
    Chiang, Chin-Lung
    Chang, Ri-Cheng
    Chiu, Yie-Chan
    [J]. THERMOCHIMICA ACTA, 2007, 453 (02) : 97 - 104
  • [4] Novel epoxy/expandable graphite halogen-free flame retardant composites-preparation, characterization, and properties
    Chiang, Chin-Lung
    Hsu, Shu-Wei
    [J]. JOURNAL OF POLYMER RESEARCH, 2010, 17 (03) : 315 - 323
  • [5] Novel efficient DOPO-based flame-retardants for PWB relevant epoxy resins with high glass transition temperatures
    Ciesielski, M.
    Schaefer, A.
    Doering, M.
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2008, 19 (06) : 507 - 515
  • [6] Feldtner N, 2004, J NON-CRYST SOLIDS, V333, P301, DOI 10.1016/j.jnoncrysol.2003.12.056
  • [7] In Situ Polymerization of Graphene, Graphite Oxide, and Functionalized Graphite Oxide into Epoxy Resin and Comparison Study of On-the-Flame Behavior
    Guo, Yuqiang
    Bao, Chenlu
    Song, Lei
    Yuan, Bihe
    Hu, Yuan
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (13) : 7772 - 7783
  • [8] Formation of highly stable dispersions of silane-functionalized reduced graphene oxide
    Hou, Shifeng
    Su, Shujun
    Kasner, Marc L.
    Shah, Pratik
    Patel, Krutika
    Madarang, Clemonne John
    [J]. CHEMICAL PHYSICS LETTERS, 2010, 501 (1-3) : 68 - 74
  • [9] Graphene/Polymer Nanocomposites
    Kim, Hyunwoo
    Abdala, Ahmed A.
    Macosko, Christopher W.
    [J]. MACROMOLECULES, 2010, 43 (16) : 6515 - 6530
  • [10] Synthesis, characterization, flame retardance and thermal properties of halogen-free expandable graphite/PMMA composites prepared from sol-gel method
    Kuan, Chen-Feng
    Yen, Wei-Hsin
    Chen, Chia-Hsun
    Yuen, Siu-Ming
    Kuan, Hsu-Chiang
    Chiang, Chin-Lung
    [J]. POLYMER DEGRADATION AND STABILITY, 2008, 93 (07) : 1357 - 1363