Recent advances in gas chromatography for solid and liquid stationary phases containing metal ions

被引：15

作者：

Rykowska, I. ^{[1
]}

Wasiak, W. ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

JOURNAL OF CHROMATOGRAPHY A | 2009年 / 1216卷 / 10期

关键词：

Complexation gas chromatography; Stationary phases; Retention mechanism; SELECTIVE COMPLEXING SORBENTS; LIGAND-EXCHANGE CHROMATOGRAPHY; CHARGE-TRANSFER INTERACTIONS; NUCLEOPHILIC COMPOUNDS; AROMATIC-HYDROCARBONS; SILICA PACKINGS; BETA-DIKETONES; COMPLEXATION; SEPARATION; CU(II);

D O I：

10.1016/j.chroma.2008.11.084

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This review is devoted to the application of metal complexes as column packings and liquid stationary phases in gas chromatography. Particular attention is paid to the stationary phases with nitrogen-containing functional groups(e.g.,amine and ketoimine)and beta-diketonates on the modified silica surface. The review also concerns the results of the research on metallomesogenes and chiral stationary phases. The factors influencing the retention mechanism in complexation gas chromatography are discussed. Practical application of the metal chelate-containing chromatographic packings for analytical separation of organic substances is considered. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1713 / 1722

页数：10

共 100 条

[1] Evaluation of transition metal complexes of aminopropylsilyl-dithiooxamide bonded phases for gas chromatography [J].