Facile route to multigram synthesis of environmentally friendly non-isocyanate polyurethanes

被引：53
作者：
Tryznowski, Mariusz [1 ]
Swiderska, Aleksandra [1 ]
Zolek-Tryznowska, Zuzanna [2 ]
Golofit, Tomasz [1 ]
Parzuchowski, Pawel G. [1 ]
机构：
[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland
[2] Warsaw Univ Technol, Fac Prod Engn, PL-02524 Warsaw, Poland
来源：
POLYMER | 2015年 / 80卷
关键词：
Non-isocyanate poly(hydroxyurethanes); Diglycerol carbonate; Clean synthesis; CYCLIC CARBONATE; POLYHYDROXYURETHANES; POLYMERIZATION; POLYADDITION; DIGLYCEROL; GLYCEROL; DIOXIDE; MONOMER;
D O I：
10.1016/j.polymer.2015.10.055
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Non-isocyanate poly(hydroxyurethanes) (NIPUs) are a fast growing class of polymers prepared by an environmentally friendly method without the use of toxic phosgene and isocyanates. In this work, we report a one-step procedure to synthesize bis(2,3-dihydroxypropyl) ether dicarbonate from a commercially available diglycerol. The product was characterized by H-1 NMR, C-13 NMR, and FTIR spectroscopies and for the first time by X-Ray diffraction measurements. Enantiomers RR and SS of the obtained monomer were observed in the single crystal structure. The bis(cyclic carbonate) monomer was used as a precursor for the synthesis of various NIPUs. The NIPUs were prepared in a non-solvent process. Spectral, thermal and rheological properties of the NIPUs formed from ten various diamines were compared. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：228 / 236
页数：9
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