Spectroscopic, structural and magnetic studies of nickel(II) complexes with tetra- and pentadentate ligands

被引：8

作者：

Patel, R. N. ^{[1
]}

Shukla, K. K. ^{[1
]}

Singh, Anurag ^{[1
]}

Choudhary, M. ^{[1
]}

Patel, D. K. ^{[2
]}

Niclos-Gutierrez, Juan ^{[2
]}

Choquesillo-Lazarte, Duane ^{[3
]}

机构：

[1] APS Univ, Dept Chem, Rewa 486003, MP, India

[2] Univ Granada, Fac Farm, Dept Quim Inorgan, E-18071 Granada, Spain

[3] IACT CSIC, Edificio Inst, Lab Estudios Cristalog, Granada 8100, Spain

来源：

TRANSITION METAL CHEMISTRY | 2009年 / 34卷 / 02期

关键词：

CONTAINING SUPEROXIDE-DISMUTASE; COPPER(II) COMPLEXES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; SCHIFF-BASE; MACROCYCLES; DNA;

D O I：

10.1007/s11243-008-9184-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new nickel(II) complexes, namely [Ni(BPSE)](BF4) 1, and [Ni(5-BST)CH3OH] ClO4 2 [BPSE = 2-benzoylpyridinesalicylidene ethylenediamine, 5-BST = 5-bromosalicylidene-tris(2-aminoethyl) amine] have been synthesized and characterized using various physicochemical methods. The magnetic and spectroscopic data indicate a distorted square planar geometry for complex 1, while complex 2 is assigned a distorted octahedral geometry. Complex 1 crystallized in the triclinic space group P-1. Complex 2 adopts an octahedral geometry with space group symmetry P 21/n. The superoxide dismutase activity of these complexes has been measured.

引用

页码：239 / 245

页数：7

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