Correlation between Asphaltene Stability in n-Heptane and Crude Oil Composition Revealed with In Situ Chemical Imaging

被引：28

作者：

Gabrienko, Anton A. ^{[1
]}

Subramani, Velu ^{[2
]}

Martyanov, Oleg N. ^{[3
]}

Kazarian, Sergei G. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England

[2] BP Prod North Amer Inc, Refining & Logist Technol, Naperville, IL 60563 USA

[3] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

来源：

ADSORPTION SCIENCE & TECHNOLOGY | 2014年 / 32卷 / 04期

关键词：

MOLECULAR-SIZE; SPECTROSCOPY; PRESSURE; MODEL;

D O I：

10.1260/0263-6174.32.4.243

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Five crude oil samples with different physical properties have been studied with respect to asphaltene stability. The attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopic imaging approach of n-heptane-induced precipitation has been used to monitor crude oil behaviour under dilution with a flocculation agent. For each sample, the dynamics of asphaltene precipitation has been observed by applying this chemical imaging method. Based on these data, the stability of crude oil samples has been compared and the correlation between asphaltene stability and crude oil properties has been proposed.

引用

页码：243 / 255

页数：13

共 48 条

[1] Relations between asphaltene structures and their physical and chemical properties:: The rosary-type structure [J].

Acevedo, Socrates ;

Castro, Alexandra ;

Negrin, Juan Gabriel ;

Fernandez, Alberto ;

Escobar, Gaston ;

Piscitelli, Vincent .

ENERGY & FUELS, 2007, 21 (04) :2165-2175

[2] INTERSTELLAR POLYCYCLIC AROMATIC-HYDROCARBONS - THE INFRARED-EMISSION BANDS, THE EXCITATION EMISSION MECHANISM, AND THE ASTROPHYSICAL IMPLICATIONS [J].

ALLAMANDOLA, LJ ;

TIELENS, AGGM ;

BARKER, JR .

ASTROPHYSICAL JOURNAL SUPPLEMENT SERIES, 1989, 71 (04) :733-775

[3]

[Anonymous], D715705 ASTM

[4]

[Anonymous], P SPE LAT AM CAR PET

[5] Structure and reactivity of petroleum-derived asphaltene [J].

Artok, L ;

Su, Y ;

Hirose, Y ;

Hosokawa, M ;

Murata, S ;

Nomura, M .

ENERGY & FUELS, 1999, 13 (02) :287-296

[6] Characterization of asphaltenes and resins from problematic Mexican crude oils [J].

Buenrostro-Gonzalez, E ;

Espinosa-Peña, M ;

Andersen, SI ;

Lira-Galeana, C .

PETROLEUM SCIENCE AND TECHNOLOGY, 2001, 19 (3-4) :299-316

[7] Detection of trace materials with fourier transform infrared spectroscopy using a multi-channel detector [J].

Chan, KLA ;

Kazarian, SG .

ANALYST, 2006, 131 (01) :126-131

[8] Effect of dense gas CO2 on the coacervation of elastin [J].

Dehghani, Fariba ;

Annabi, Nasim ;

Valtchev, Peter ;

Mithieux, Suzanne M. ;

Weiss, Anthony S. ;

Kazarian, Sergei G. ;

Tay, Feng H. .

BIOMACROMOLECULES, 2008, 9 (04) :1100-1105

[9] In Situ Chemical Imaging of Asphaltene Precipitation from Crude Oil Induced by n-Heptane [J].

Gabrienko, Anton A. ;

Lai, Chen H. ;

Kazarian, Sergei G. .

ENERGY & FUELS, 2014, 28 (02) :964-971

[10] Asphaltene-paraffin structural interactions.: Effect on crude oil stability [J].

García, MD ;

Carbognani, L .

ENERGY & FUELS, 2001, 15 (05) :1021-1027

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