Ferroelectric properties were investigated for (100), (110), and (111)-single-oriented rhombohedral Pb(Zr0.65Ti0.35)O-3 films. Saturation polarization, P-sat, was changed by the simple tilting angle of the polar axis from the film surface normal. On the other hand, (100)- and (11 (1) over bar)/(111)-oriented films prepared on (100) Si substrates showed similar P-sat values due to the coexistence of (11 (1) over bar) orientation. The coercive field, E-c, of rhombohedral Pb(Zr0.65Ti0.35)O-3 films was lower than that of tetragonal Pb(Zr0.4Ti0.6)O-3 films. (100)-oriented rhombohedral films with SrRuO3 electrodes did not show noticeable degradation in polarization up to 10(10) switching cycles. These results show that (100)-oriented rhombohedral Pb(ZrxTi1-x)O-3 film is available to realize the low voltage operated ferroelectric random access memory instead of the present tetragonal Pb(ZrxTi1-x)O-3 films. (C) 2014 The Japan Society of Applied Physics
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Symetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United KingdomSymetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United Kingdom
Jiang, A.Q.
Scott, J.F.
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Symetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United KingdomSymetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United Kingdom
Scott, J.F.
Dawber, M.
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Symetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United KingdomSymetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United Kingdom
Dawber, M.
Wang, C.
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Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, ChinaSymetrix Centre for Ferroics, Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, United Kingdom