Photoelectrochemical Detection of H2O2 Based on FlowerLike CuInS2-Graphene Hybrid

被引:21
作者
Wang, Siwen [1 ]
Zhu, Yihua [1 ]
Yang, Xiaoling [1 ]
Li, Chunzhong [1 ]
机构
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China
基金
中国国家自然科学基金;
关键词
Flower-like CuInS2; Graphene; Photoelectrochemistry; Horseradish peroxidase; Biosensors; CUINS2; THIN-FILMS; HYDROGEN-PEROXIDE; HORSERADISH-PEROXIDASE; QUANTUM DOTS; BIOSENSOR; NANOPARTICLES; SENSOR; NANOTUBES; ELECTRODE; GROWTH;
D O I
10.1002/elan.201300515
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel photoelectrochemcial biosensing system was fabricated based on the composition of horseradish peroxidase (HRP), flower-like CuInS2 (CIS) and graphene on indium tin oxide (ITO) electrode for detecting H2O2. The graphene layer was used as highly conductive scaffolds for electron transport from the ITO electrode to CIS. Furthermore, the flower-like CIS enhanced the multi-reflection of light and provided matrixes for the adsorption of HRP. Utilizing one-pot solvothermal method, we prepared flower-like CIS-graphene hybrid (GCIS). Electrochemical tests displayed advantage of graphene with better electron conductivity, and HRP/GCIS showed higher photoelectrochemical behavior.
引用
收藏
页码:573 / 580
页数:8
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