Synthesis, characterization, and surface studies of conjugated polymers possessing 2,2′-biimidazole moieties

被引：6

作者：

Walker, D. T. ^{[1
]}

Douglas, C. D. ^{[1
]}

MacLean, B. J. ^{[1
]}

机构：

[1] St Francis Xavier Univ, Dept Chem, Antigonish, NS B2G 2W5, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2009年 / 87卷 / 06期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

imidazole; conjugated polymer; electropolymerization; SPECTROSCOPIC CHARACTERIZATION; THIOPHENE POLYMER; DERIVATIVES; COMPLEXES; FILMS; CONDUCTIVITY; RU; OS;

D O I：

10.1139/V09-055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel 2,2'-biimidazole-thiophene structures, 5,5'-bis(2,2'-bithiophene-5-yl)-1,1'-dimethyl-2,2'-biimidazole and 5,5'-bis(3,4-ethylenedioxythiophene-2-yl)-1,1'-dimethyl-2,2'-biimidazole, have been synthesized and electrochemically polymerized. These materials underwent facile oxidation on Pt and ITO surfaces in CH2Cl2/Bu4NPF6 to yield conjugated, electroactive polymer films. The films were characterized with cyclic voltammetry, electronic absorption spectroscopy, and atomic force microscopy.

引用

页码：729 / 737

页数：9

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