Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

被引：28

作者：

Nisula, Mikko ^{[1
]}

Linnera, Jarno ^{[1
]}

Karttunen, Antti J. ^{[1
]}

Karppinen, Maarit ^{[1
]}

机构：

[1] Aalto Univ, Dept Chem & Mat Sci, Aalto 00076, Finland

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 13期

基金：

欧洲研究理事会; 芬兰科学院;

关键词：

atomic layer deposition; coordination polymer; lithium organic hybrid; molecular layer deposition; thin film; ATOMIC/MOLECULAR LAYER DEPOSITION; ORGANIC FRAMEWORK MATERIALS; COORDINATION POLYMER; METAL-IONS; NETWORKS; CRYSTAL; FREQUENCIES; DIRECTIONS; STATE;

D O I：

10.1002/chem.201605816

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

引用

页码：2988 / 2992

页数：5

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