Characterization of Functionalized Imidazolium Ionic Liquids and Their Lithium Salt Solutions

被引：6

作者：

Egashira, Minato ^{[1
]}

Sumimoto, Michinori ^{[1
]}

Yoshimoto, Nobuko ^{[1
]}

Morita, Masayuki ^{[1
]}

Hori, Kenji ^{[1
]}

机构：

[1] Yamaguchi Univ, Grad Sch Sci & Engn, Yamaguchi 7558611, Japan

来源：

ELECTROCHEMISTRY | 2009年 / 77卷 / 03期

关键词：

Ionic Liquid; Imidazolium Ion; Functionalization; Conductivity; TEMPERATURE MOLTEN-SALTS; ELECTROLYTES; BATTERIES; CONDUCTIVITY; ADDITIVES;

D O I：

10.5796/electrochemistry.77.237

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

On ionic liquids having functional groups in the side chain of their imidazolium cations, their characterization has been carried out. The ion conduction properties of the lithium salt solutions of these ionic liquids have also been investigated Proton NMR measurement reveals that CmMI cation has a tendency of charge localization than other imidazolium cations. Among the ionic liquids investigated, only the one having CmMI cation exhibit conductivity increase when it dissolves small amount of lithium salt. Raman spectra for the lithium salt solutions indicate that the CmMI-based ionic liquid provides different status of lithium ion compared with EMI-based ionic liquid. Such a difference appears to come from the difference in electronic structure of imidazolium cation.

引用

页码：237 / 240

页数：4

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