Synthesis of unsymmetrical benzoporphyrazines in functional ionic liquids and formation of self-aggregates of zinc(II) pyridino[3,4]tribenzoporphyrazines in solutions

被引：18

作者：

Chauhan, S. M. S. ^{[1
]}

Kumari, Pratibha ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Delhi 110007, India

来源：

TETRAHEDRON | 2009年 / 65卷 / 12期

关键词：

Unsymmetrical benzoporphyrazines; Subphthalocyanines; Ionic liquids; Assembly; Thermal hearing; Ring enlargement; Complexes; EFFICIENT SYNTHESIS; PHOTODYNAMIC ACTIVITY; COORDINATION POLYMER; IRON(III) PORPHYRINS; CARBONYL-COMPOUNDS; PHTHALOCYANINES; METAL; SUBPHTHALOCYANINES; OXIDATION; ASSEMBLIES;

D O I：

10.1016/j.tet.2009.01.046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unsymmetrically substituted metal-free and metallated benzoporphyrazines including pyridino[3,4]-tribenzoporphyrazinic macrocycles have been synthesized in good yields by ring expansion reactions of boron(III) subphthalocyanines with phthalonitriles in functional ammonium ionic liquids in the presence of 1,8-diazabicyclo-[5,4,0]-undec-7-ene (DBU) under different reaction conditions. The concentration dependent UV/vis, fluorescence, NMR and ESI-MS spectroscopic data indicate that zinc(II) pyridino[3,4]tribenzoporphyrazines exist as head-to-tail self-aggregates in the solution phase. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2518 / 2524

页数：7

共 79 条

[1] 1,4-dibutoxy-2,3-di(4-pyridyl)-8,11,15,18,22,25-hexakis(hexyl)-phthalocyaninato zinc, a self-assembled coordination polymer in the solid state [J].